247138
氯羰基亚磺酰氯
96%
别名:
(氯巯基)甲酰氯, 氯甲酰亚磺酰氯
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线性分子式:
ClCOSCl
化学文摘社编号:
分子量:
130.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-415-2
Beilstein/REAXYS Number:
506318
MDL number:
Assay:
96%
Form:
liquid
InChI key
MNOALXGAYUJNKX-UHFFFAOYSA-N
InChI
1S/CCl2OS/c2-1(4)5-3
SMILES string
ClSC(Cl)=O
assay
96%
form
liquid
refractive index
n20/D 1.517 (lit.)
bp
98 °C (lit.)
density
1.552 g/mL at 25 °C (lit.)
functional group
chloro
storage temp.
2-8°C
Quality Level
Application
氯羰基亚磺酰氯已用于制备：
- 5-(1,2,3,4-四-O-乙酰-α-D-吡喃木糖-5S-C-基)-1,3,4-氧杂噻唑-2-酮
- 氟化的oxathialones
- 聚氟烷基-硫代氯甲酸
- 氯羰基聚氟烷基次磺酸酯
- 氯羰基六氟异丙叉基亚氨次磺酸
- 5-三-氟甲基-2-氧代-1,3,4-氧杂噻唑
- 具有重要商业价值的N,N-二烷基氨甲酰氯化物
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
An improved one-pot cost-effective synthesis of N, N-disubstituted carbamoyl halides and derivatives.
Adeppa K, et al.
Canadian Journal of Chemistry, 88(!2), 1277-1280 (2010)
Keith G McMillan et al.
Carbohydrate research, 341(1), 41-48 (2005-11-03)
5-(1,2,3,4-tetra-O-acetyl-alpha-D-xylopyranos-5S-C-yl)-1,3,4-oxathiazol-2-one (8) has been prepared from glucuronamide in two steps and 73% overall yield by conversion to the tetra-O-acetyl derivative 7 followed by reaction with chlorocarbonylsulfenyl chloride. 5-(2,3,4-Tri-O-acetyl-beta-D-xylopyranosyl)-1,3,4-oxathiazol-2-one (12) was synthesised from D-xylose by a four-step sequence involving conversion to
Some fluorinated heterocyclic and acyclic derivatives of chlorocarbonylsulfenyl chloride.
John EO and Jean'ne MS.
Journal of Fluorine Chemistry, 36(4), 429-438 (1987)
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