247197
甲基乙烯基砜
≥97%
别名:
1-甲磺酰基乙烯, 乙烯基甲基砜, 甲基乙烯基砜, 甲磺酰乙烯, （甲磺酰基）乙烯
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关于此项目
线性分子式:
H2C=CHSO2CH3
化学文摘社编号:
分子量:
106.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
222-958-0
MDL number:
Assay:
≥97%
Form:
liquid
InChI key
WUIJTQZXUURFQU-UHFFFAOYSA-N
InChI
1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3
SMILES string
CS(=O)(=O)C=C
assay
≥97%
form
liquid
contains
0.02% p-tert-butylphenol as stabilizer
refractive index
n20/D 1.463 (lit.)
bp
115-117 °C/19 mmHg (lit.)
density
1.212 g/mL at 25 °C (lit.)
functional group
sulfone
storage temp.
2-8°C
Gene Information
human ... LOC129293(129293)
Application
已使用甲基乙烯基砜：
- 作为衍生化试剂的改进方法，使用毛细管 HPLC-质谱法测定核苷混合物中的假尿苷
- 棉织物迈克尔加成法制备甲基磺酰基乙基纤维素
- 卤代芳烃的赫克乙烯化
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Eye Dam. 1
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
>235.4 °F - closed cup
flash_point_c
> 113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis, 3495-3495 (2006)
K L Dearfield et al.
Mutagenesis, 6(6), 519-525 (1991-11-01)
Over the past several years, we have been evaluating the mutagenicity and clastogenicity of compounds capable of Michael-type reactions. These compounds, including acrylamide, several acrylate and methacrylate esters, vinyl sulfones, and phorone, have been evaluated using TK+/- -3.7.2C mouse lymphoma
M D Shelby et al.
Mutation research, 250(1-2), 431-437 (1991-09-01)
Methyl vinyl sulfone and divinyl sulfone were tested for the induction of dominant lethal mutations and micronucleated bone-marrow erythrocytes in male mice. These chemicals were chosen for study because of their similarities in structure and chemical reactivity to acrylamide which
G B Gordon et al.
Carcinogenesis, 12(12), 2393-2396 (1991-12-01)
The induction of quinone reductase [QR; NAD(P)H:(quinone acceptor) oxidoreductase; EC 1.6.99.2] in cultured cells and animal tissues of rodents has provided useful information on mechanisms of protection against carcinogens. We have developed a simple and efficient microtiter plate assay for
Gert Emmerechts et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 825(2), 233-238 (2005-07-21)
A method is presented for improved detection of pseudouridine in nucleoside mixtures based on the specific derivatization with methyl vinyl sulfone followed by analysis by capillary HPLC-mass spectrometry. Reaction conditions were optimized in order to obtain the best yield and
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