247197
甲基乙烯基砜
≥97%
别名:
1-甲磺酰基乙烯, 乙烯基甲基砜, 甲基乙烯基砜, 甲磺酰乙烯, （甲磺酰基）乙烯
方案
≥97%
表单
liquid
包含
0.02% p-tert-butylphenol as stabilizer
折射率
n20/D 1.463 (lit.)
沸点
115-117 °C/19 mmHg (lit.)
密度
1.212 g/mL at 25 °C (lit.)
官能团
sulfone
储存温度
2-8°C
SMILES字符串
CS(=O)(=O)C=C
InChI
1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3
InChI key
WUIJTQZXUURFQU-UHFFFAOYSA-N
基因信息
human ... LOC129293(129293)
应用
已使用甲基乙烯基砜：
- 作为衍生化试剂的改进方法，使用毛细管 HPLC-质谱法测定核苷混合物中的假尿苷
- 棉织物迈克尔加成法制备甲基磺酰基乙基纤维素
- 卤代芳烃的赫克乙烯化
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Dermal - Acute Tox. 4 Oral - Eye Dam. 1
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
>235.4 °F - closed cup
闪点(°C)
> 113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
K L Dearfield et al.
Mutagenesis, 6(6), 519-525 (1991-11-01)
Over the past several years, we have been evaluating the mutagenicity and clastogenicity of compounds capable of Michael-type reactions. These compounds, including acrylamide, several acrylate and methacrylate esters, vinyl sulfones, and phorone, have been evaluated using TK+/- -3.7.2C mouse lymphoma
Structural components in methyl vinyl sulfone modified cotton cellulose.
Rowland SP, et al.
Canadian Journal of Chemistry, 44(9), 1051-1058 (1966)
T J Warr et al.
Mutation research, 245(3), 191-199 (1990-11-01)
Methyl vinyl sulphone (MVS) is a labile, Michael-reactive chemical, similar in structure to acrylamide (AA). Given that acrylamide is a reference mammalian mutagen and a rodent carcinogen, studies were undertaken to evaluate the potential genotoxicity of MVS. In common with
M D Shelby et al.
Mutation research, 250(1-2), 431-437 (1991-09-01)
Methyl vinyl sulfone and divinyl sulfone were tested for the induction of dominant lethal mutations and micronucleated bone-marrow erythrocytes in male mice. These chemicals were chosen for study because of their similarities in structure and chemical reactivity to acrylamide which
Gert Emmerechts et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 825(2), 233-238 (2005-07-21)
A method is presented for improved detection of pseudouridine in nucleoside mixtures based on the specific derivatization with methyl vinyl sulfone followed by analysis by capillary HPLC-mass spectrometry. Reaction conditions were optimized in order to obtain the best yield and
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