248533
5-降冰片烯-2-甲醇
98%, mixture of endo and exo
别名:
2-(羟甲基)双环[2.2.1]庚-5-烯, 2-羟甲基-5-降冰片烯, 2-降冰片烯-5-甲醇, 5-(羟甲基)双环[2.2.1]庚-2-烯, 5-羟甲基-2-降冰片烯, [双环[2.2.1]庚-5-烯-2-基]甲醇, 双环[2.2.1]庚-5-烯-2-联苯基甲醇, 降冰片烯-5-甲醇
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关于此项目
经验公式（希尔记法）:
C8H12O
化学文摘社编号:
分子量:
124.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-392-0
MDL number:
产品名称
5-降冰片烯-2-甲醇, 98%, mixture of endo and exo
InChI key
LUMNWCHHXDUKFI-KJFJCRTCSA-N
InChI
1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2/t6-,7+,8?/m0/s1
SMILES string
OCC1C[C@@H]2C[C@H]1C=C2
assay
98%
form
liquid
refractive index
n20/D 1.500 (lit.)
bp
97 °C/20 mmHg (lit.)
density
1.027 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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Application
5-降冰片烯-2-甲醇已用于制备：
- 4-(降冰片-2-烯-5-基亚甲氧基）)-2,2′:6′,2′′-吡啶
- 5- {[(3,5-二-叔丁基-4-羟基-苯甲酰基)氧基]甲基} -2-降冰片烯 (BHBN)
General description
目前已有报道称，使用多相二氧化硅支撑的催化剂可将 5-降冰片烯-2-甲醇与乙烯共聚。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
188.6 °F - closed cup
flash_point_c
87 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Access to heterogeneous atom-transfer radical polymerization (ATRP) catalysts based on dipyridylamine and terpyridine via ring-opening metathesis polymerization (ROMP).
Kroll R, et al.
Macromolecular Chemistry and Physics, 202(5), 645-653 (2001)
Synthesis of a polynorbornene containing 3, 5-di-TERT-butyl-4-hydroxybenzoyl group.
Tienkopatchev MA, et al.
Polymer Bull., 34(4), 385-391 (1995)
Homogeneous and heterogeneous metallocene/MAO-catalyzed polymerization of functionalized olefins.
Goretzki R and Fink G.
Macromolecular Chemistry and Physics, 200(4), 881-886 (1999)
Zhen Zhang et al.
Polymers, 12(4) (2020-04-16)
Injectable, covalently cross-linked hydrogels have been widely investigated in drug delivery systems due to their superior mechanical properties and long-term stability. Conventional covalently cross-linked hydrogels are formed by chemical reactions that may interfere with natural biochemical processes. In this work
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