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248533

5-降冰片烯-2-甲醇

98%, mixture of endo and exo

别名:

2-(羟甲基)双环[2.2.1]庚-5-烯, 2-羟甲基-5-降冰片烯, 2-降冰片烯-5-甲醇, 5-(羟甲基)双环[2.2.1]庚-2-烯, 5-羟甲基-2-降冰片烯, [双环[2.2.1]庚-5-烯-2-基]甲醇, 双环[2.2.1]庚-5-烯-2-联苯基甲醇, 降冰片烯-5-甲醇

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关于此项目

经验公式（希尔记法）:
C8H12O
化学文摘社编号:
95-12-5
分子量:
124.18
NACRES:
NA.22
PubChem Substance ID:
24854934
UNSPSC Code:
12352100
EC Number:
202-392-0
MDL number:
MFCD00167571
Assay:
98%
Form:
liquid
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Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.500 (lit.)

bp

97 °C/20 mmHg (lit.)

density

1.027 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

OCC1C[C@@H]2C[C@H]1C=C2

InChI

1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2/t6-,7+,8?/m0/s1

InChI key

LUMNWCHHXDUKFI-KJFJCRTCSA-N

General description

目前已有报道称，使用多相二氧化硅支撑的催化剂可将 5-降冰片烯-2-甲醇与乙烯共聚。

Application

5-降冰片烯-2-甲醇已用于制备：
  • 4-(降冰片-2-烯-5-基亚甲氧基）)-2,2′:6′,2′′-吡啶
  • 5- {[(3,5-二-叔丁基-4-羟基-苯甲酰基)氧基]甲基} -2-降冰片烯 (BHBN)

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

188.6 °F - closed cup

flash_point_c

87 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCL3556
MKBV0238V
MKBD8135V
MKBD8135
MKBB1650

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Zhen Zhang et al.
Polymers, 12(4) (2020-04-16)
Injectable, covalently cross-linked hydrogels have been widely investigated in drug delivery systems due to their superior mechanical properties and long-term stability. Conventional covalently cross-linked hydrogels are formed by chemical reactions that may interfere with natural biochemical processes. In this work
Homogeneous and heterogeneous metallocene/MAO-catalyzed polymerization of functionalized olefins.
Goretzki R and Fink G.
Macromolecular Chemistry and Physics, 200(4), 881-886 (1999)
Access to heterogeneous atom-transfer radical polymerization (ATRP) catalysts based on dipyridylamine and terpyridine via ring-opening metathesis polymerization (ROMP).
Kroll R, et al.
Macromolecular Chemistry and Physics, 202(5), 645-653 (2001)
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全球贸易项目编号

货号GTIN
248533-5G04061837331602