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248940

S-联萘酚磷酸酯

Name: <I>S</I>-联萘酚磷酸酯
Brand: ALDRICH

97%

别名:

(S)-(+)-1,1′-联萘-2,2′-二基磷酸氢酯, (S)-4-羟基二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-氧化物

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关于此项目

经验公式（希尔记法）:

C₂₀H₁₃O₄P

化学文摘社编号:

35193-64-7

分子量:

348.29

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24854963

MDL number:

MFCD00010045

Beilstein/REAXYS Number:

4787775

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属性

Quality Level

100

assay

97%

form

solid

optical activity

[α]22/D +595°, c = 1.35 in methanol

functional group

phosphate

SMILES string

OP1(=O)Oc2ccc3ccccc3c2-c4c(O1)ccc5ccccc45

InChI

1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)

InChI key

JEHUZVBIUCAMRZ-UHFFFAOYSA-N

说明

Application

用作不对称 Mannich 反应中手性布朗斯特酸催化剂。

pictograms

GHS07

signalword

Warning

hcodes

H315

pcodes

P302 + P352

Hazard Classifications

Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Chiral Phosphoric Acids: Versatile Organocatalysts with Expanding Applications

TRIP and TiPSY Chiral Phosphoric Acid Catalysts

手性磷酸：用途广泛的多功能有机催化剂

TRIP和TiPSY手性磷酸催化剂

A comparison of ionic liquids to molecular organic solvents as additives for chiral separations in micellar electrokinetic chromatography.

Simon M Mwongela et al.

Journal of separation science, 30(9), 1334-1342 (2007-07-12)

In this study, we report the effects of adding ionic liquids (ILs), as compared to adding conventional molecular organic solvents (MOSs), to aqueous buffer solutions containing molecular micelles in the separation of chiral analyte mixtures in micellar EKC (MEKC). The

Enantioseparation of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate in capillary electrophoresis by using di- and oligosaccharides as chiral selectors: di- and oligosaccharide chiral selectors in capillary electrophoresis.

B Chankvetadze et al.

Chirality, 10(1-2), 134-139 (1998-02-21)

Twelve different disaccharides and a series of noncyclic malto- and cello-oligosaccharides were used as chiral selectors in capillary electrophoresis (CE). Most saccharides resolved the enantiomers of atropisomeric 1,1'-binaphthyl-2,2'-diyl hydrogen phosphate (BDHP) depending on the type (alpha or beta) and position

Chiral Brønsted acid catalyzed enantioselective Mannich-type reaction.

Masahiro Yamanaka et al.

Journal of the American Chemical Society, 129(21), 6756-6764 (2007-05-05)

Mannich-type reaction of ketene silyl acetals with aldimines proceeded catalytically by means of a phosphoric acid diester, derived from (R)-BINOL, as a chiral Brønsted acid to afford beta-amino esters with good diastereoselectivity in favor of the syn isomer and high

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全球贸易项目编号

货号	GTIN
248940-1G	04061825928425
248940-5G	04061825928432