249440
氢肉桂酰氯
98%
别名:
3-苯基丙酰氯
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关于此项目
线性分子式:
C6H5CH2CH2COCl
化学文摘社编号:
分子量:
168.62
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-443-6
Beilstein/REAXYS Number:
742586
MDL number:
产品名称
氢肉桂酰氯, 98%
form
liquid
assay
98%
SMILES string
ClC(=O)CCc1ccccc1
InChI key
MFEILWXBDBCWKF-UHFFFAOYSA-N
InChI
1S/C9H9ClO/c10-9(11)7-6-8-4-2-1-3-5-8/h1-5H,6-7H2
refractive index
n20/D 1.5265 (lit.)
bp
107 °C/11 mmHg (lit.)
mp
−7-−5 °C (lit.)
density
1.135 g/mL at 25 °C (lit.)
functional group
acyl chloride
phenyl
Quality Level
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Application
氢肉桂酰氯已用于：
- 防污剂（+）-马来酸内酯 A 的对映选择性合成
- 氢肉桂酰基-法呢基-L-半胱氨酸甲酯的合成
General description
已经通过循环伏安法研究了在含有高氯酸四烷基铵的乙腈中的汞阴极处的氢肉桂酰氯的还原。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Aquatic Chronic 3 - Skin Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Electrochemical reduction of phenylacetyl chloride and hydrocinnamoyl chloride at mercury cathodes in acetonitrile.
Mubarak MS, et al.
Journal of Electroanalytical Chemistry, 350(1), 205-216 (1993)
Onovughode T Oboh et al.
Journal of biochemical and molecular toxicology, 22(1), 51-62 (2008-02-15)
The C-terminal --COOH of prenylated proteins is methylated to --COOCH3. The --COOCH3 ester forms are hydrolyzed by prenylated methylated protein methyl esterase (PMPMEase) to the original acid forms. This is the only reversible step of the prenylation pathway. PMPMEase has
Richard J Duffy et al.
The Journal of organic chemistry, 74(13), 4772-4781 (2009-05-21)
A novel class of small spirocyclic heterocycles, spiroepoxy-beta-lactones (1,4-dioxaspiro[2.3]-hexan-5-ones), is described that exhibit a number of interesting reactivity patterns. These spiroheterocycles, including an optically active series, are readily synthesized by epoxidation of ketene dimers (4-alkylidene-2-oxetanones) available from homo- or heteroketene
Abbas D Farahani et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 20(7), 972-983 (2019-02-21)
To investigate the role of the capping group in the solution and solid-state self-assembly of short peptide amphiphiles, dialanine and diphenylalanine have been linked via the N-terminus to a benzene (phenyl) and 3-naphthyl capping groups using three different methylene linkers;
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