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249440

氢肉桂酰氯

98%

别名:

3-苯基丙酰氯

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关于此项目

线性分子式:
C6H5CH2CH2COCl
化学文摘社编号:
645-45-4
分子量:
168.62
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24854993
EC Number:
211-443-6
Beilstein/REAXYS Number:
742586
MDL number:
MFCD00000748
Assay:
98%
Form:
liquid
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Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.5265 (lit.)

bp

107 °C/11 mmHg (lit.)

mp

−7-−5 °C (lit.)

density

1.135 g/mL at 25 °C (lit.)

functional group

acyl chloride, phenyl

SMILES string

ClC(=O)CCc1ccccc1

InChI

1S/C9H9ClO/c10-9(11)7-6-8-4-2-1-3-5-8/h1-5H,6-7H2

InChI key

MFEILWXBDBCWKF-UHFFFAOYSA-N

General description

已经通过循环伏安法研究了在含有高氯酸四烷基铵的乙腈中的汞阴极处的氢肉桂酰氯的还原。

Application

氢肉桂酰氯已用于：
  • 防污剂（+）-马来酸内酯 A 的对映选择性合成
  • 氢肉桂酰基-法呢基-L-半胱氨酸甲酯的合成

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Aquatic Chronic 3 - Skin Irrit. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBF5666V
STBD0575V
STBB3456V
S63890
STBB8993V

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Onovughode T Oboh et al.
Journal of biochemical and molecular toxicology, 22(1), 51-62 (2008-02-15)
The C-terminal --COOH of prenylated proteins is methylated to --COOCH3. The --COOCH3 ester forms are hydrolyzed by prenylated methylated protein methyl esterase (PMPMEase) to the original acid forms. This is the only reversible step of the prenylation pathway. PMPMEase has
Richard J Duffy et al.
The Journal of organic chemistry, 74(13), 4772-4781 (2009-05-21)
A novel class of small spirocyclic heterocycles, spiroepoxy-beta-lactones (1,4-dioxaspiro[2.3]-hexan-5-ones), is described that exhibit a number of interesting reactivity patterns. These spiroheterocycles, including an optically active series, are readily synthesized by epoxidation of ketene dimers (4-alkylidene-2-oxetanones) available from homo- or heteroketene
Electrochemical reduction of phenylacetyl chloride and hydrocinnamoyl chloride at mercury cathodes in acetonitrile.
Mubarak MS, et al.
Journal of Electroanalytical Chemistry, 350(1), 205-216 (1993)
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全球贸易项目编号

货号GTIN
249440-5G04061825928579
249440-25G04061836683481