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249491

三(4-氯苯基)膦

Name: 三(4-氯苯基)膦
Brand: ALDRICH

95%, powder

别名:

NSC 136459, Tris(p-chlorophenyl)phosphine

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关于此项目

线性分子式:

(ClC₆H₄)₃P

化学文摘社编号:

1159-54-2

分子量:

365.62

NACRES:

NA.22

PubChem Substance ID:

24854999

UNSPSC Code:

12352101

EC Number:

214-596-7

MDL number:

MFCD00013639

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属性

产品名称

三(4-氯苯基)膦, 95%

Quality Level

100

assay

95%

form

powder

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings

mp

100-103 °C (lit.)

functional group

phosphine

SMILES string

Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3

InChI

1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

InChI key

IQKSLJOIKWOGIZ-UHFFFAOYSA-N

说明

Application

Catalyst for:

Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
Solvent-free Heck reactions

Cocatalyst in:

Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
Rhodium-catalyzed hydrogenation reactions
Platinum-catalyzed allylation reactions