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Merck
CN

249785

2-溴丙酰溴

97%

别名:

α-溴丙酰基溴, α-溴丙酰溴, (±)-2-溴丙酰溴, 2-溴丙酰溴

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关于此项目

线性分子式:
CH3CHBrCOBr
化学文摘社编号:
分子量:
215.87
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-261-7
Beilstein/REAXYS Number:
1071331
MDL number:
Assay:
97%
Form:
liquid
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vapor density

7.5 (vs air)

Quality Level

vapor pressure

1.3 mmHg ( 20 °C)

assay

97%

form

liquid

refractive index

n20/D 1.518 (lit.)

bp

48-50 °C/10 mmHg (lit.)

density

2.061 g/mL at 25 °C (lit.)

functional group

acyl bromide, bromo

SMILES string

CC(Br)C(Br)=O

InChI

1S/C3H4Br2O/c1-2(4)3(5)6/h2H,1H3

InChI key

ILLHORFDXDLILE-UHFFFAOYSA-N

Application

2-溴丙酰基溴已用于合成:
  • 纤维素在氯化 1-烯丙基-3-甲基咪唑离子液体中直接酰化引发剂
  • 3-(2-溴丙酰基)-2-恶唑烷酮衍生物
  • 端溴酯基的聚(3-己基噻吩),用作丙烯酸酯的原子转移自由基聚合的大引发剂 。


pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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A highly stereoselective synthesis of a key intermediate of 1?-methylcarbapenems employing the reformatsky reaction of 3-(2-bromopropionyl)-2-oxazolidone derivatives.
Ito Y and Terashima S.
Tetrahedron Letters, 28(52), 6625-6628 (1987)
Xiaofeng Sui et al.
Biomacromolecules, 9(10), 2615-2620 (2008-09-09)
Cellulose-graft-poly(N,N-dimethylamino-2-ethyl methacrylate) (cellulose-g-PDMAEMA) copolymers were prepared by homogeneous atom transfer radical polymerization (ATRP) under mild conditions. Cellulose macroinitiator was successfully synthesized by direct acylation of cellulose with 2-bromopropionyl bromide in a room temperature ionic liquid (RTIL), 1-allyl-3-methylimidazolium chloride. Copolymers were
Regioregular poly (3-alkylthiophene) conducting block copolymers.
Iovu MC, et al.
Polymer, 46(19), 8582-8586 (2005)



全球贸易项目编号

货号GTIN
249785-500G04061825928753
249785-100G04061825928746