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249904

3,3-二甲基烯丙基溴

Name: 3,3-二甲基烯丙基溴
Brand: ALDRICH

technical grade, ~90%

别名:

1-溴-3-甲基-2-丁烯, 溴代异戊烯

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关于此项目

线性分子式:

(CH₃)₂C=CHCH₂Br

化学文摘社编号:

870-63-3

分子量:

149.03

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24855022

EC Number:

212-799-5

Beilstein/REAXYS Number:

1420778

MDL number:

MFCD00000242

Assay:

~90%

Form:

liquid

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属性

grade

technical grade

Quality Level

200

assay

~90%

form

liquid

contains

silver wool as stabilizer

refractive index

n20/D 1.489 (lit.)

bp

82-83 °C/150 mmHg (lit.)

density

1.29 g/mL at 20 °C (lit.)

functional group

alkyl halide, bromo

storage temp.

2-8°C

SMILES string

C\C(C)=C\CBr

InChI

1S/C5H9Br/c1-5(2)3-4-6/h3H,4H2,1-2H3

InChI key

LOYZVRIHVZEDMW-UHFFFAOYSA-N

说明

Application

3,3-Dimethylallyl bromide has been used in the preparation of:

(±)-eldanolide
1-(3,3-dimethylallyl)-L-tryptophan
(±)-fumagillin, antibiotic isolated from Aspergillus fumigattus

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pictograms

GHS02,GHS05,GHS09

signalword

Danger

hcodes

H226,H314,H410

pcodes

P210 - P233 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

104.0 °F - closed cup

flash_point_c

40 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A direct synthesis of (?)-eldanolide via the highly regioselective prenylation of 2-trimethylsiloxyfuran.

Jefford CW, et al.

Tetrahedron Letters, 28(9), 949-950 (1987)

A total synthesis of ( )-fumagillin.

E J Corey et al.

Journal of the American Chemical Society, 94(7), 2549-2550 (1972-04-05)

Biosynthesis of aromatic isoprenoids. Part 5. The preparation of 1-(3, 3-dimethylallyl)-L-tryptophan and cyclo-L-aianyl-1-(3, 3-dimethylallyl)-L-tryptophan and their non-incorporation into echinulin.

Grundon MF, et al.

Journal of the Chemical Society. Perkin Transactions 1, 1294-1298 (1980)

全球贸易项目编号

货号	GTIN
249904-5G	04061825936734
249904-25G	04061825936727