249904
3,3-二甲基烯丙基溴
technical grade, ~90%
别名:
1-溴-3-甲基-2-丁烯, 溴代异戊烯
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关于此项目
线性分子式:
(CH3)2C=CHCH2Br
化学文摘社编号:
分子量:
149.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-799-5
Beilstein/REAXYS Number:
1420778
MDL number:
Assay:
~90%
Form:
liquid
InChI key
LOYZVRIHVZEDMW-UHFFFAOYSA-N
InChI
1S/C5H9Br/c1-5(2)3-4-6/h3H,4H2,1-2H3
SMILES string
C\C(C)=C\CBr
grade
technical grade
assay
~90%
form
liquid
contains
silver wool as stabilizer
Quality Level
bp
82-83 °C/150 mmHg (lit.)
density
1.29 g/mL at 20 °C (lit.)
functional group
alkyl halide, bromo
storage temp.
2-8°C
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Application
3,3-Dimethylallyl bromide has been used in the preparation of:
- (±)-eldanolide
- 1-(3,3-dimethylallyl)-L-tryptophan
- (±)-fumagillin, antibiotic isolated from Aspergillus fumigattus
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
104.0 °F - closed cup
flash_point_c
40 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
A direct synthesis of (?)-eldanolide via the highly regioselective prenylation of 2-trimethylsiloxyfuran.
Jefford CW, et al.
Tetrahedron Letters, 28(9), 949-950 (1987)
A total synthesis of ( )-fumagillin.
E J Corey et al.
Journal of the American Chemical Society, 94(7), 2549-2550 (1972-04-05)
Biosynthesis of aromatic isoprenoids. Part 5. The preparation of 1-(3, 3-dimethylallyl)-L-tryptophan and cyclo-L-aianyl-1-(3, 3-dimethylallyl)-L-tryptophan and their non-incorporation into echinulin.
Grundon MF, et al.
Journal of the Chemical Society. Perkin Transactions 1, 1294-1298 (1980)
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