Merck
CN

250031

Sigma-Aldrich

(R)-N-3,5-二硝基苯甲酰基苯甘氨酸

99%

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别名:
N-(3,5-二硝基苯甲酰)-D-α-苯基甘氨酸, R-(-)-N-(3,5-二硝基苯甲酰)-α-苯基甘氨酸
线性分子式:
(O2N)2C6H3CONHCH(C6H5)CO2H
CAS号:
分子量:
345.26
Beilstein:
4719763
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

检测方案

99%

旋光性

[α]20/D −102°, c = 0.9 in THF

reaction suitability

reaction type: solution phase peptide synthesis

mp

216-217 °C (lit.)

application(s)

peptide synthesis

SMILES string

OC(=O)[C@H](NC(=O)c1cc(cc(c1)[N+]([O-])=O)[N+]([O-])=O)c2ccccc2

InChI

1S/C15H11N3O7/c19-14(16-13(15(20)21)9-4-2-1-3-5-9)10-6-11(17(22)23)8-12(7-10)18(24)25/h1-8,13H,(H,16,19)(H,20,21)/t13-/m1/s1

InChI key

MIVUDAUOXJDARR-CYBMUJFWSA-N

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

法规信息

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Wolfgang Thormann et al.
Journal of pharmaceutical and biomedical analysis, 27(3-4), 555-567 (2002-01-05)
The electrokinetic separation and analysis of the enantiomers of albendazole sulfoxide (ABZSO), a sulfoxide with a sulfur stereogenic center hepatically formed during therapy with the anthelmintic drug albendazole (ABZ), is reported. Using aqueous or nonaqueous alkaline background electrolytes, ABZSO enantiomers
Resolution of enantiomers of 19-hydroxyeicosatetraenoate and 18-hydroxyeicosatetraenoate by chiral phase high-performance liquid chromatography of naphthoyl ester derivatives.
E H Oliw
Journal of chromatography, 526(2), 525-529 (1990-04-06)
K H Gahm et al.
Analytical chemistry, 67(1), 19-25 (1995-01-01)
Regiospecifically monosubstituted 1-(1-naphthyl)ethylcarbamoylated beta-cyclodextrins (NEC-beta-CDs) were successfully employed as chiral additives in capillary zone electrophoresis (CZE) to achieve chiral separation of N-(3,5-dinitrobenzoyl)phenylglycine (3,5-DNB-PG), phenylalanine (3,5-DNB-PA), and homophenylalanine (3,5-DNB-HPA). The enantioselectivity of the various site-substituted NEC-beta-CDs in CZE was compared with
K Roy et al.
Drug design and discovery, 17(4), 315-323 (2002-01-05)
QSAR analyses of matrix metalloproteinase (MMP) inhibitor N-[(substituted phenyl)sulfonyl]-N-4-nitrobenzylglycine hydroxamates, recently reported by Scozzafava and Supuran, have been attempted using linear free energy related (LFER) model of Hansch to explore the contribution patterns of the phenyl ring substitutions (P1' anchoring
S K Yang et al.
Journal of chromatography, 371, 195-209 (1986-12-26)
The direct resolution of K-region cis- and trans-dihydrodiol enantiomers of 14 unsubstituted and methyl- and bromo-substituted benz[a]anthracene (BA) derivatives was investigated by high-performance liquid chromatography with commercially available columns, packed with gamma-aminopropylsilanized silica to which either (R)-N-(3,5-dinitrobenzoyl)phenylglycine (R-DNBPG) or (S)-N-(3,5-dinitrobenzoyl)leucine

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