250996
2-氯-N,N-二乙基乙酰胺
97%
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关于此项目
线性分子式:
ClCH2CON(C2H5)2
化学文摘社编号:
分子量:
149.62
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
219-019-2
MDL number:
Assay:
97%
Form:
liquid
产品名称
2-氯-N,N-二乙基乙酰胺, 97%
InChI key
CQQUWTMMFMJEFE-UHFFFAOYSA-N
InChI
1S/C6H12ClNO/c1-3-8(4-2)6(9)5-7/h3-5H2,1-2H3
SMILES string
CCN(CC)C(=O)CCl
assay
97%
form
liquid
refractive index
n20/D 1.47 (lit.)
bp
148-150 °C/55 mmHg (lit.)
density
1.089 g/mL at 25 °C (lit.)
application(s)
agriculture
environmental
Quality Level
Application
2-Chloro-N,N-diethylacetamide has been used in:
- preparation of calixarene amides
- synthesis of 5-bromo-25,26,27,28-tetrakis[(N,N-diethylaminocarbonyl)-methoxy]calix[4]arene
- synthesis of amide calix[4]pyrrole macrocycles with super-extended cavities
- microwave-assisted organic synthesis of 3-cyano-N,N-diethyl-4-(4-methoxyphenoyl)-4-oxobutanamide
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
[Local and skin resorptive action of N,N-diethylchloracetamide].
V A Shugaev et al.
Gigiena truda i professional'nye zabolevaniia, (2)(2), 51-52 (1989-01-01)
[Data on hygienic standardization of N,N-diethyl-2-chloroacetamide in the air of the work area].
V A Shugaev et al.
Gigiena truda i professional'nye zabolevaniia, (6)(6), 36-37 (1991-01-01)
Dewei Tang et al.
Tetrahedron letters, 51(35), 4595-4598 (2010-08-07)
We herein report a dramatically improved total synthesis of the high-affinity translocator protein (TSPO) ligand DPA-714, featuring microwave-assisted organic synthesis (MAOS). Compared with previously described approaches, our novel MAOS method dramatically reduces overall reaction time without adversely effecting reaction yields.
Synthesis and crystal structures of lower rim amine and carbamoyl substituted calixarenes as transfer agents for oxyanions between an aqueous and a chloroform phase.
Wolf NJ, et al.
Polyhedron, 18(6), 855-896 (1999)
Synthesis and properties of new calixarene-based ditopic receptors for the simultaneous complexation of cations and carboxylate anions.
Pelizzi N, et al.
J. Chem. Soc. Perkin Trans. II, 6, 1307-1312 (1998)
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