25170
1-(氯甲基)萘
technical, ≥97.0% (GC)
别名:
1-萘甲基氯
等级
technical
质量水平
方案
≥97.0% (GC)
表单
solid
颜色
deep brown
折射率
n20/D 1.635 (lit.)
n20/D 1.635
沸点
167-169 °C/25 mmHg (lit.)
mp
32 °C (lit.)
密度
1.18 g/mL at 25 °C (lit.)
官能团
chloro
SMILES字符串
ClCc1cccc2ccccc12
InChI
1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2
InChI key
XMWGTKZEDLCVIG-UHFFFAOYSA-N
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一般描述
Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
269.6 °F - closed cup
闪点(°C)
132 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)
Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.
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