25170
1-(氯甲基)萘
technical, ≥97.0% (GC)
别名:
1-萘甲基氯
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关于此项目
线性分子式:
C10H7CH2Cl
化学文摘社编号:
分子量:
176.64
EC Number:
201-678-2
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
Beilstein/REAXYS Number:
636885
MDL number:
Assay:
≥97.0% (GC)
Form:
solid
产品名称
1-(氯甲基)萘, technical, ≥97.0% (GC)
InChI key
XMWGTKZEDLCVIG-UHFFFAOYSA-N
InChI
1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2
SMILES string
ClCc1cccc2ccccc12
grade
technical
assay
≥97.0% (GC)
form
solid
color
deep brown
refractive index
n20/D 1.635 (lit.)
n20/D 1.635
bp
167-169 °C/25 mmHg (lit.)
mp
32 °C (lit.)
density
1.18 g/mL at 25 °C (lit.)
functional group
chloro
Quality Level
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General description
Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
269.6 °F - closed cup
flash_point_c
132 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)
Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.
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