25170
1-(氯甲基)萘
technical, ≥97.0% (GC)
别名:
1-萘甲基氯
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关于此项目
线性分子式:
C10H7CH2Cl
化学文摘社编号:
分子量:
176.64
EC Number:
201-678-2
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
Beilstein/REAXYS Number:
636885
MDL number:
Assay:
≥97.0% (GC)
Form:
solid
InChI key
XMWGTKZEDLCVIG-UHFFFAOYSA-N
InChI
1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2
SMILES string
ClCc1cccc2ccccc12
grade
technical
assay
≥97.0% (GC)
form
solid
color
deep brown
refractive index
n20/D 1.635 (lit.), n20/D 1.635
bp
167-169 °C/25 mmHg (lit.)
mp
32 °C (lit.)
density
1.18 g/mL at 25 °C (lit.)
functional group
chloro
Quality Level
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General description
Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
269.6 °F - closed cup
flash_point_c
132 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Bo Peng et al.
Organic letters, 13(19), 5402-5405 (2011-09-14)
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η(3)-benzylpalladium intermediates.
Formation kinetics and spectra of aromatic radicals in solution.
Kelley DF, et al.
The Journal of Physical Chemistry, 87(11), 1842-1843 (1983)
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