产品名称
氯二氟乙酸酐, 98%
InChI key
VBJIFLOSOQGDRZ-UHFFFAOYSA-N
InChI
1S/C4Cl2F4O3/c5-3(7,8)1(11)13-2(12)4(6,9)10
SMILES string
FC(F)(Cl)C(=O)OC(=O)C(F)(F)Cl
assay
98%
form
liquid
refractive index
n20/D 1.347 (lit.)
bp
96-97 °C (lit.)
density
1.395 g/mL at 25 °C (lit.)
functional group
anhydride
chloro
ester
fluoro
Quality Level
Application
Chlorodifluoroacetic anhydride has been used:
- for dual element acetylation tagging derivatization of amines by using microwave sustained helium emission detector
- as derivatization reagent in determination of estrone and 17β-estradiol in hair by GC-MS
General description
Photolysis of the vapour of chlorodifluoroacetic anhydride has been studied over the range 19-201°C using 248nm radiation.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Skin Corr. 1B
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
M H Choi et al.
The Analyst, 125(4), 711-714 (2000-07-13)
An efficient procedure is described for the determination of estrone and 17 beta-estradiol in hair by gas chromatography-mass spectrometry (GC-MS). The method involves alkyloxycarbonylation with isobutyl chloroformate (isoBCF) of phenolic hydroxy groups after alkaline digestion of hair samples. The resulting
Photochemistry of anhydrides. Part 6.-Photolysis of chlorodifluoroacetic anhydride,(CF 2 ClCO) 2 O.
Watkins PE and Whittle E.
J. Chem. Soc., Faraday, 80(8), 2323-2329 (1984)
Multi-element taggant and dual homolog derivatization concepts in GC/MED.
Hagen DF, et al.
Spectrochimica Acta. Part B: Atomic Spectroscopy, 40(1), 335-347 (1985)
Courtney T Jollymore-Hughes et al.
Bioorganic & medicinal chemistry, 24(21), 5270-5279 (2016-09-18)
Association of cholinesterase with β-amyloid plaques and tau neurofibrillary tangles in Alzheimer's disease offers an opportunity to detect disease pathology during life. Achieving this requires development of radiolabelled cholinesterase ligands with high enzyme affinity. Various fluorinated acetophenone derivatives bind to
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