252301
8-溴-1-辛烯
97%
别名:
1-Bromo-7-octene, 7-Octen-1-yl bromide, 7-Octenyl bromide
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关于此项目
线性分子式:
Br(CH2)6CH=CH2
化学文摘社编号:
分子量:
191.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-268-4
Beilstein/REAXYS Number:
2234481
MDL number:
产品名称
8-溴-1-辛烯, 97%
InChI key
SNMOMUYLFLGQQS-UHFFFAOYSA-N
InChI
1S/C8H15Br/c1-2-3-4-5-6-7-8-9/h2H,1,3-8H2
SMILES string
BrCCCCCCC=C
assay
97%
form
liquid
refractive index
n20/D 1.467 (lit.)
density
1.139 g/mL at 25 °C (lit.)
functional group
alkyl halide
allyl
bromo
Quality Level
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Application
8-Bromo-1-octene has been used in preparation of polymerizable ligand, required for the synthesis of quantum dot-labelled polymer beads. Grignard reagent derived from 8-bromo-1-octene has been used in the synthesis of (2S,3S,5R)-5-[(1R)-1-hydroxy-9-decenyl]-2-pentyltetrahydro-3-furanol. It has been used as building block in natural product synthesis.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
172.4 °F - closed cup
flash_point_c
78 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Christophe Dubost et al.
Organic letters, 8(22), 5137-5140 (2006-10-20)
The total synthesis of the polyhydroxylated macrolide (+)-aspicilin 5 is described using as a key step a highly diastereoselective allylation of aldehyde 6 with the uniquely functionalized allylstannane 1. (+)-Aspicilin is obtained in 18 steps and 10% overall yield. [structure:
Enantiocontrolled synthesis of C-19 tetrahydrofurans isolated from the marine alga Notheia anomala.
Garci'a C, et al.
Tetrahedron Letters, 41(21), 4127-4130 (2000)
Paul O'Brien et al.
Chemical communications (Cambridge, England), (20)(20), 2532-2533 (2003-11-05)
CdSe quantum dots with polymerisable ligands have been incorporated into polystyrene beads, via a suspension polymerisation reaction, as a first step towards the optical encoding of solid supports for application in solid phase organic chemistry.
Carolyn A Leverett et al.
The Journal of organic chemistry, 71(22), 8591-8601 (2006-10-27)
cis-2-Methyl-6-substituted piperidin-3-ol alkaloids of the Cassia and Prosopis species are readily prepared by a combination of an aza-Achmatowicz oxidative rearrangement and dihydropyridone reduction followed by a stereoselective allylsilane addition to a N-sulfonyliminium ion. The stereochemical outcome of the reduction reaction
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