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Merck
CN

252387

Sigma-Aldrich

五氟丙酸酐

99%

别名:

PFPA, 全氟丙酸酐

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线性分子式:
(CF3CF2CO)2O
化学文摘社编号:
分子量:
310.05
Beilstein:
1806446
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案

99%

表单

liquid

沸点

69-70 °C/735 mmHg (lit.)

密度

1.571 g/mL at 25 °C (lit.)

官能团

anhydride
ester
fluoro

SMILES字符串

FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16

InChI key

XETRHNFRKCNWAJ-UHFFFAOYSA-N

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应用

五氟丙酸酐:
  • 用于制备酚酸卤代衍生物,需要测定脑脊液中的一些生物重要酸
  • 用作GC-多离子检测法检测未处理大鼠脑内内源性胺1,2,3,4-四氢异喹啉和1-甲基-1,2,3,4-四氢异喹啉的衍生化试剂
  • 用于通过气液相色谱法同时测定大鼠纹状体多巴胺的主要代谢产物

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

补充剂危害

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
C Jurado et al.
Forensic science international, 145(2-3), 161-166 (2004-09-29)
This paper describes a procedure for the detection and quantification of ethyl-glucuronide (EtG) in hair samples. During method development the efficacy of extraction of EtG from hair was compared in four extraction methods: (a) methanol; (b) methanol:water (1:1); (c) water;
G F Grinstead
Journal of analytical toxicology, 15(6), 293-298 (1991-11-01)
PFPA and acetic anhydride derivatives of morphine and codeine were evaluated with respect to stability, chromatography, potential for analytical interferences by other opiates, and suitability of major fragment ions for analysis by GC/MS with deuterated internal standards and selected ion
J L Villamor et al.
Journal of analytical toxicology, 29(2), 135-139 (2005-05-21)
A new gas chromatography-mass spectrometry method for the simultaneous identification and quantitation of amphetamine (AP), methamphetamine (MA), 3,4-methylenedioxyamphetamine (MDA), 3,4-methylenedioxymethamphetamine (MDMA), and 3,4-methylenedioxyethamphetamine (MDEA) in hair is proposed. Hair was hydrolyzed in 1 M NaOH at 40 degrees C, subjected

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