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About This Item
线性分子式:
Al(C2H5)3
CAS Number:
分子量:
114.16
Beilstein:
3587229
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
应用
Triethylaluminum solution can be used:
- As a reagent in Alumino-Mannich reaction, where it reacts with iminium ion substrates for which the corresponding Petasis borono-Mannich reaction is unsuccessful.
- In the synthesis of macrocyclic binuclear aluminum complexes with efficient activities toward ring-opening polymerization of ε-caprolactone.
- To promote Claisen rearrangement of allyl vinyl ether derivatives along with the transfer of ethyl group to aldehydic carbon.
- As a reagent for copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams.
- As a precursor to synthesize diethylaluminium cyanide, which is used as hydrocyanating reagent.
警示用语:
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Self-heat. 2 - Skin Corr. 1A - STOT SE 3 - Water-react 1
靶器官
Respiratory system
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
-0.4 °F - closed cup
闪点(°C)
-18 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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