质量水平
方案
97%
表单
liquid
折射率
n20/D 1.615 (lit.)
沸点
113 °C/15 mmHg (lit.)
密度
1.094 g/mL at 25 °C (lit.)
官能团
ketone
储存温度
−20°C
SMILES字符串
O=C1C=CC=CC=C1
InChI
1S/C7H6O/c8-7-5-3-1-2-4-6-7/h1-6H
InChI key
QVWDCTQRORVHHT-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
金属催化的[6+3]环烷与偶氮甲亚胺环加成反应已被报道。
应用
环庚三烯酮已被用于合成：
- 通过杂环卡宾催化的[8+3]环化途径合成双环δ-内酯
- 通过热加成至苄基合成6,7-苯并双环[3.2.2]壬基-3,6,8-三烯-2-酮
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
Y Nakagawa et al.
Chemico-biological interactions, 116(1-2), 45-60 (1999-01-07)
The mechanism of mitochondrial dysfunction and toxicity induced by the tropolones, beta-thujaplicin (4-isopropyl tropolone), tropolone and tropone, has been studied in freshly isolated rat hepatocytes. Incubation of hepatocytes with beta-thujaplicin (1-4 mM) elicited a concentration and time-dependent cell killing. The
L Isakovic et al.
Organic letters, 3(26), 4189-4192 (2002-01-11)
The carbocyclic core of CP-225,917 and CP-263,114 is accessible through the [6+4] cycloaddition of a tropone with a 2-substituted cyclopentadiene. Examination of this reaction has revealed for the first time that this cycloaddition process is catalyzed by Lewis acids, including
Vijay Nair et al.
The Journal of organic chemistry, 71(23), 8964-8965 (2006-11-04)
A novel protocol for the annulation of tropone to enals involving nucleophilic heterocyclic carbene (NHC) catalyzed homoenolate formation has been developed. Interestingly, the reaction led to bicyclic delta-lactones instead of the expected gamma-spirolactones, presumably by the uncommon [8 + 3]
K P Randau et al.
Die Pharmazie, 64(5), 350-351 (2009-06-18)
Two tropone derivatives, orobanone (1), previously isolated from Orobanche rapum-genistae, and the new natural product pernambucone (3,8-dimethyl-5-isopropyl-2,3-dihydro-1H-azulene-1,6-dione, 2), were isolated from the sterm bark of Croton argyroglossum. The structures were elucidated from spectroscopic data.
Barry M Trost et al.
Journal of the American Chemical Society, 130(45), 14960-14961 (2008-10-22)
The cyanosubstituted trimethylenemethane donor undergoes palladium-catalyzed [6 + 3] cycloaddition with a variety of tropones to yield bicyclo[4.3.1]decadienes in excellent regio-, diastereo-, and enantioselectivity. Products of the Pd-TMM [6 + 3] cycloaddition participate in a thermal [3,3] sigmatropic rearrangement to
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持