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Merck
CN

253189

三(二乙氨基)膦

97%, liquid

别名:

三(N,N-二乙氨基)膦, 三(二乙基氨基)膦, 亚磷酸三(二乙酰胺), 六乙基三氨基磷酸酯, 六乙基三胺磷, 六乙基亚磷酰三胺

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关于此项目

线性分子式:
P[N(C2H5)2]3
化学文摘社编号:
分子量:
247.36
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
EC Number:
218-920-8
MDL number:
Beilstein/REAXYS Number:
636187
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产品名称

三(二乙氨基)膦, 97%

Quality Level

assay

97%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.475 (lit.)

bp

80-90 °C/10 mmHg (lit.)

density

0.903 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CCN(CC)P(N(CC)CC)N(CC)CC

InChI

1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3

InChI key

FDIOSTIIZGWENY-UHFFFAOYSA-N

Application

三(二乙氨基)膦[(Et2N)3P]可作为试剂,合成以下物质:
  • 1,1′-二烷基异靛蓝衍生物,通过脱氧反应与各种1-烷基异丁烯反应进行合成。
  • 1-氨基甲基靛红,通过靛红与伯胺和仲胺反应合成。

也可用于通过富勒烯C60对某些环状 α-二酮进行脱氧。


pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

flash_point_f

138.2 °F - closed cup

flash_point_c

59 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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全球贸易项目编号

货号GTIN
253189-25G04061825982151
253189-5G04061838047380