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经验公式(希尔记法):
C24H32O8
化学文摘社编号:
分子量:
448.51
Beilstein:
1693744
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
一般描述
二苯并-24-冠8-醚是一种大环化合物,可与金属离子形成络合物增强其溶解性和反应性,在有机合成中有多种功能。也用作各种有机反应的相转移催化剂,包括有机碳酸酯的合成与酚的烷基化反应。
应用
二苯并-24-冠-8可作为transporter,用于合成噻唑基单支和三支轮烷。也用作共溶剂和相转移催化剂,配合氟化铯建立更高效的有机合成无水氟化体系。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
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Mateusz Woźny et al.
Dalton transactions (Cambridge, England : 2003), 48(19), 6546-6557 (2019-04-24)
[2]rotaxanes composed of a dibenzo-24-crown-8 wheel (DB24C8) and an axle containing two metal-complexing tetraazamacrocyclic units linked with a p-xylylene bridge, coordinating the same or different metal ions (Ni and/or Cu) are described. A symmetric di-Ni rotaxane crystallizes in the monoclinic
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Travis B Gasa et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(1), 106-116 (2008-12-17)
Paraquat bis(hexafluorophosphate) undergoes stepwise dissociation in acetone. All three species-the neutral molecule, and the mono- and dications-are represented significantly under the experimental conditions typically used in host-guest binding studies. Paraquat forms at least four host-guest complexes with dibenzo[24]crown-8. They are
Xiaofan Ji et al.
Journal of the American Chemical Society, 135(1), 74-77 (2012-12-25)
A supramolecular cross-linked network was fabricated and demonstrated to act as a multiple fluorescent sensor. It was constructed from a fluorescent conjugated polymer and a bisammonium salt cross-linker driven by dibenzo[24]crown-8/secondary ammonium salt host-guest interactions. Compared with the conjugated polymer
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