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Merck
CN

254142

氯化铋 (III)

99.99% trace metals basis

别名:

三氯化铋, 三氯铋

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经验公式(希尔记法):
BiCl3
化学文摘社编号:
分子量:
315.34
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
232-123-2
MDL number:
Assay:
99.99% trace metals basis
Form:
solid
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assay

99.99% trace metals basis

form

solid

reaction suitability

core: bismuth, reagent type: catalyst

impurities

≤150.0 ppm Trace Metal Analysis

bp

447 °C (lit.)

mp

230-232 °C (lit.)

application(s)

material synthesis precursor
perovskite solar cells

SMILES string

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

InChI key

JHXKRIRFYBPWGE-UHFFFAOYSA-K

General description

Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi3+ ions used in various organic transformations and synthesis of bismuth nanomaterials.

Application

Bismuth(III) chloride can be used:
  • As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance.
  • As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs2AgBiBr6 and Cs2AgBiCl6, eco-friendly alternative to the lead halide perovskites.
  • To form a protective layer on anode materials.
It can also be used as an efficient catalyst for green synthesis of:
  • Chalcones by Claisen–Schmidt reaction under solvent-free conditions.
  • One-pot three-component synthesis of Propargylamines.
  • Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters.


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

The prevailing strategies for heat and electric-power production that rely on fossil and fission fuels are having a negative impact on the environment and on our living conditions.

相关内容

Learn how low-cost bismuth catalysts are transforming organic synthesis. Discover innovative applications, gain expert insights, and learn practical strategies for organobismuth chemistry.


An efficient green protocol for the synthesis of chalcones by a Claisen-Schmidt reaction using bismuth (III) chloride as a catalyst under solvent-free condition
Dhruva Kumar, et al.
Green Chemistry Letters and Reviews, 3, 283-286 (2010)
Organic-inorganic nanohybrids as novel thermoelectric materials: hybrids of polyaniline and bismuth (III) telluride nanoparticles
Naoki Toshima, et al.
Journal of Electronic Materials, 40, 898-902 (2011)
A bismuth-based protective layer for magnesium metal anode in noncorrosive electrolytes
Yimin Zhao, et al.
ACS Energy Letters, 6, 2594-2601 (2021)



全球贸易项目编号

货号GTIN
254142-25G04061825983769