氯化铋 (III)

Name: 氯化铋 (III)
Brand: ALDRICH

99.99% trace metals basis

别名:

三氯化铋, 三氯铋

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经验公式（希尔记法）:

BiCl₃

化学文摘社编号:

7787-60-2

分子量:

315.34

NACRES:

NA.23

PubChem Substance ID:

24855360

UNSPSC Code:

12352302

EC Number:

232-123-2

MDL number:

MFCD00003461

Assay:

99.99% trace metals basis

Form:

solid

主要文件

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产品名称

氯化铋 (III), 99.99% trace metals basis

InChI key

JHXKRIRFYBPWGE-UHFFFAOYSA-K

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

SMILES string

Cl[Bi](Cl)Cl

assay

99.99% trace metals basis

form

solid

reaction suitability

core: bismuth
reagent type: catalyst

impurities

≤150.0 ppm Trace Metal Analysis

bp

447 °C (lit.)

mp

230-232 °C (lit.)

application(s)

material synthesis precursor
perovskite solar cells

Quality Level

100

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Application

Bismuth(III) chloride can be used:

As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance.
As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs₂AgBiBr₆ and Cs₂AgBiCl₆, eco-friendly alternative to the lead halide perovskites.
To form a protective layer on anode materials.

It can also be used as an efficient catalyst for green synthesis of:

Chalcones by Claisen–Schmidt reaction under solvent-free conditions.
One-pot three-component synthesis of Propargylamines.
Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters.

General description

Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi³⁺ ions used in various organic transformations and synthesis of bismuth nanomaterials.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319

pcodes

P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Cs2AgBiX6 (X= Br, Cl): new visible light absorbing, lead-free halide perovskite semiconductors

Eric T McClure, et al.

Chemistry of Materials, 28, 1348-1354 (2016)

An efficient green protocol for the synthesis of chalcones by a Claisen-Schmidt reaction using bismuth (III) chloride as a catalyst under solvent-free condition

Dhruva Kumar, et al.

Green Chemistry Letters and Reviews, 3, 283-286 (2010)

Organic-inorganic nanohybrids as novel thermoelectric materials: hybrids of polyaniline and bismuth (III) telluride nanoparticles

Naoki Toshima, et al.

Journal of Electronic Materials, 40, 898-902 (2011)

A bismuth-based protective layer for magnesium metal anode in noncorrosive electrolytes

Yimin Zhao, et al.

ACS Energy Letters, 6, 2594-2601 (2021)

A simple and efficient one-pot three-component synthesis of propargylamines using bismuth (III) chloride

Abbas Teimouri, et al.

Bulletin of the Korean Chemical Society,, 33, 1556-1560 (2012)

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Thermoelectric Performance of Perovskite-type Oxide Materials

The prevailing strategies for heat and electric-power production that rely on fossil and fission fuels are having a negative impact on the environment and on our living conditions.

氯化铋 (III)

99.99% trace metals basis

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关于此项目

主要文件

属性

产品名称

InChI key

InChI

SMILES string

assay

form

reaction suitability

impurities

bp

mp

application(s)

Quality Level

相关类别

说明

Application

General description

安全信息

pictograms

signalword

hcodes

pcodes

Hazard Classifications

存储类别

wgk

flash_point_f

flash_point_c

ppe

文件

分析证书(COA)

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