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254185

溴化铜

99.999% trace metals basis

别名:

一溴化铜

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关于此项目

线性分子式:
CuBr
化学文摘社编号:
7787-70-4
分子量:
143.45
NACRES:
NA.23
PubChem Substance ID:
24855364
UNSPSC Code:
12352302
EC Number:
232-131-6
MDL number:
MFCD00010969
Assay:
99.999% trace metals basis
Form:
powder
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assay

99.999% trace metals basis

form

powder

reaction suitability

core: copper, reagent type: catalyst

impurities

≤15.0 ppm Trace Metal Analysis

mp

504 °C (lit.)

density

4.71 g/mL at 25 °C (lit.)

SMILES string

[Cu]Br

InChI

1S/BrH.Cu/h1H;/q;+1/p-1

InChI key

NKNDPYCGAZPOFS-UHFFFAOYSA-M

General description

溴化亚铜(I)是一种淡绿色的无机抗磁性固体，具有像硫化锌一样的聚合结构。不溶于水，广泛应用于催化、纳米材料合成和太阳能电池等领域。

Application

溴化亚铜(I)可用于：
  • 作为有机太阳能电池（OSC）的溶液可加工空穴传输层（HTL）。CuBr可提高太阳能电池的能量转换效率。
  • 作为合成光致发光金属有机框架（MOF）的前体。
  • 合成高发光性三配位铜(I)配合物作为OLED的掺杂剂，其最大外部量子效率为21.3%。
  • 与配体作为催化剂在14种不同溶剂中进行叔烷基卤化物的原子转移自由基聚合（ATRP）反应，测定速率常数。
  • 分子内自由基陷阱辅助原子转移自由基偶联法合成大环聚合物。

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000426770
0000426770
0000391142
0000325847
0000391142

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实验方案

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

An acs-Type Metal--Organic Framework with an Unprecedented Undecanuclear Copper Cluster as Secondary Building Unit
Sheng Hu, et al.
European Journal of Inorganic Chemistry, 2012, 3669-3673 (2012)
Highly Efficient Green Organic Light-Emitting Diodes Containing Luminescent Three-Coordinate Copper(I) Complexes
Masashi Hashimoto, et al.
Journal of the American Chemical Society, 133, 10348-10351 (2011)
Carla Sardo et al.
International journal of pharmaceutics, 563, 347-357 (2019-04-03)
Sustained pulmonary delivery of tobramycin from microparticles composed of drug/polymer nanocomplexes offers several advantages against traditional delivery methods. Namely, in patients with cystic fibrosis, microparticle delivery can protect the tobramycin being delivered from strong mucoadhesive interactions, thus avoiding effects on
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全球贸易项目编号

货号GTIN
254185-10G04061825983790
254185-100G04061833595862