254940
甲基乙酰亚胺酯 盐酸盐
technical grade
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线性分子式:
CH3C(=NH)OCH3 · HCl
化学文摘社编号:
分子量:
109.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
238-843-3
Beilstein/REAXYS Number:
3671581
MDL number:
产品名称
甲基乙酰亚胺酯 盐酸盐, technical grade
InChI key
WHYJXXISOUGFLJ-UHFFFAOYSA-N
InChI
1S/C3H7NO.ClH/c1-3(4)5-2;/h4H,1-2H3;1H
SMILES string
Cl.COC(C)=N
grade
technical grade
mp
105 °C (dec.) (lit.)
functional group
amine
storage temp.
2-8°C
Quality Level
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General description
Methyl acetimidate hydrochloride is an inhibitor of N-methylation of phosphatidylethanolamine. It also prevents the stimulation of purified cardiac sarcolemmal vesicles Ca2+-pump activities.
Application
Methyl acetimidate hydrochloride has been used in pre-crystallization chemical modification of lysine residues.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
K C Flanders et al.
Biochemistry, 21(18), 4244-4251 (1982-08-31)
N epsilon-Acetimidoglucagon to be used for semisynthesis was prepared by reacting glucagon with methyl acetimidate hydrochloride at pH 10.2, favoring acetimidation of the sole epsilon-amino group. N epsilon-Acetimidoglucagon was isolated from the crude acetimidoglucagon mixture by anion-exchange chromatography at pH
G J van Scharrenburg et al.
Biochemistry, 23(25), 6285-6294 (1984-12-04)
To study the structural importance of the NH2-terminal Ala1 residue of pancreatic phospholipase A2, several mutants were prepared by a stepwise semisynthetic approach. 13C NMR spectroscopy of 90%-enriched [[3-13C]Ala1] phospholipases A2 shows the pK values of the alpha-NH3+ groups of
L C Packman et al.
The Biochemical journal, 193(2), 525-539 (1981-02-01)
Two variants of chloramphenicol acetyltransferase which are specified by genes on plasmids found in Gram-negative bacteria were subjected to amidination with methyl acetimidate to determine the relative reactivity of surface lysine residues and to search for unreactive or "buried" amino
Michael R Shortreed et al.
Analytical chemistry, 78(18), 6398-6403 (2006-09-15)
A powerful approach to relative quantification by mass spectrometry is to employ labeling reagents that target specific functional groups in molecules of interest. A quantitative comparison of two or more samples may be readily accomplished by using a chemically identical
V Panagia et al.
Biochimica et biophysica acta, 856(2), 383-387 (1986-04-14)
Incubation of purified cardiac sarcolemmal vesicles (SL) in the presence of S-adenosyl-L-methionine, a methyl donor for the enzymatic N-methylation of phosphatidylethanolamine (PE), increased the Ca2+-stimulated ATPase and ATP-dependent Ca2+ accumulation activities. Quantitative analysis of the methylated phospholipids revealed that maximal
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