255114
3-硝基苯甲醚
99%
别名:
1-甲氧基-3-硝基苯
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关于此项目
线性分子式:
O2NC6H4OCH3
化学文摘社编号:
分子量:
153.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-079-8
Beilstein/REAXYS Number:
1865326
MDL number:
Assay:
99%
Form:
solid
InChI key
WGYFINWERLNPHR-UHFFFAOYSA-N
InChI
1S/C7H7NO3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3
SMILES string
COc1cccc(c1)[N+]([O-])=O
assay
99%
form
solid
bp
121-123 °C/8 mmHg (lit.)
mp
36-38 °C (lit.)
solubility
alcohol: soluble(lit.), water: insoluble(lit.)
General description
Photoinduced nucleophilic substitution reactions of 3-nitroanisole in the presence of OH− in mixtures of H2O and CH3CN and in the presence of OCH3− in CH3OH were investigated by nanosecond time-resolved absorption spectroscopy. 3-Nitroanisole undergoes photoreaction with n-butylamine to yield 3-nitrophenol. It forms a 1:1 inclusion complex with β-cyclodextrin in aqueous buffer solution at pH 12.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Modification of an intermolecular photoreaction by cyclodextrin: the photohydroxylation of 3-nitroanisole.
Evans CH and Gunnlaugsson T.
Journal of Photochemistry and Photobiology A: Chemistry, 78(1), 57-62 (1994)
Nitrophenyl ethers as possible photoaffinity labels. The nucleophilic aromatic photosubstitution revisited.
Cervelo J., et al.
Tetrahedron Letters, 25(37), 4147-4150 (1984)
Spectroscopic and kinetic study of the photoinduced methoxy substitution of 3-nitroanisole and 3, 5-dinitroanisole.
Van Zeijl PHM, et al.
Journal of Photochemistry, 29(3), 415-433 (1985)
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