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255114

3-硝基苯甲醚

Name: 3-硝基苯甲醚
Brand: ALDRICH

99%

别名:

1-甲氧基-3-硝基苯

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关于此项目

线性分子式:

O₂NC₆H₄OCH₃

化学文摘社编号:

555-03-3

分子量:

153.14

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24855288

EC Number:

209-079-8

Beilstein/REAXYS Number:

1865326

MDL number:

MFCD00007237

Assay:

99%

Form:

solid

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属性

assay

99%

form

solid

bp

121-123 °C/8 mmHg (lit.)

mp

36-38 °C (lit.)

solubility

alcohol: soluble(lit.), water: insoluble(lit.)

SMILES string

COc1cccc(c1)[N+]([O-])=O

InChI

1S/C7H7NO3/c1-11-7-4-2-3-6(5-7)8(9)10/h2-5H,1H3

InChI key

WGYFINWERLNPHR-UHFFFAOYSA-N

说明

General description

Photoinduced nucleophilic substitution reactions of 3-nitroanisole in the presence of OH⁻ in mixtures of H₂O and CH₃CN and in the presence of OCH₃⁻ in CH₃OH were investigated by nanosecond time-resolved absorption spectroscopy. 3-Nitroanisole undergoes photoreaction with n-butylamine to yield 3-nitrophenol. It forms a 1:1 inclusion complex with β-cyclodextrin in aqueous buffer solution at pH 12.

pictograms

GHS07

signalword

Warning

hcodes

H302

pcodes

P301 + P312 + P330

Hazard Classifications

Acute Tox. 4 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Spectroscopic and kinetic study of the photoinduced methoxy substitution of 3-nitroanisole and 3, 5-dinitroanisole.

Van Zeijl PHM, et al.

Journal of Photochemistry, 29(3), 415-433 (1985)

Modification of an intermolecular photoreaction by cyclodextrin: the photohydroxylation of 3-nitroanisole.

Evans CH and Gunnlaugsson T.

Journal of Photochemistry and Photobiology A: Chemistry, 78(1), 57-62 (1994)

Nitrophenyl ethers as possible photoaffinity labels. The nucleophilic aromatic photosubstitution revisited.

Cervelo J., et al.

Tetrahedron Letters, 25(37), 4147-4150 (1984)

全球贸易项目编号

货号	GTIN
255114-5G	04061832099088