255165
三丁基甲基氯化铵 溶液
75 wt. % in H2O
别名:
甲基三丁基氯化铵 溶液
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关于此项目
线性分子式:
CH3N[CH3(CH2)3]3Cl
化学文摘社编号:
分子量:
235.84
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
7.9 mmHg ( 25 °C)
质量水平
浓度
75 wt. % in H2O
折射率
n20/D 1.4682
沸点
152 °C
密度
0.964 g/mL at 25 °C
SMILES字符串
[Cl-].CCCC[N+](C)(CCCC)CCCC
InChI
1S/C13H30N.ClH/c1-5-8-11-14(4,12-9-6-2)13-10-7-3;/h5-13H2,1-4H3;1H/q+1;/p-1
InChI key
IPILPUZVTYHGIL-UHFFFAOYSA-M
一般描述
三丁基甲基氯化铵(TBMAC)是一种季铵盐,常用作各种有机合成反应的相转移催化剂。也用于制备离子液体。
应用
三丁基甲基氯化铵溶液可作为相转移催化剂,用于在KHSO5氧化剂存在下,经由环己酮的Baeyer-Villiger氧化反应合成ɛ-己内酯。
警示用语:
Warning
危险分类
Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
New and efficient technique for the synthesis of ?-caprolactone using KHSO5 as an oxidising agent in the presence of a phase transfer catalyst
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Applied Catalysis A: General, 395(1-2), 49-52 (2011)
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