255718
氟化铯
99.99% trace metals basis
别名:
NSC 84270
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关于此项目
经验公式（希尔记法）:
CsF
化学文摘社编号:
分子量:
151.90
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
236-487-3
MDL number:
Assay:
99.99% trace metals basis
Form:
solid
Solubility:
methanol: slightly soluble(lit.), pyridine: insoluble(lit.)
Quality Level
assay
99.99% trace metals basis
form
solid
impurities
≤150.0 ppm Trace Metal Analysis
mp
682 °C (lit.)
solubility
methanol: slightly soluble(lit.), pyridine: insoluble(lit.)
density
4.115 g/mL at 25 °C (lit.)
SMILES string
[F-].[Cs+]
InChI
1S/Cs.FH/h;1H/q+1;/p-1
InChI key
XJHCXCQVJFPJIK-UHFFFAOYSA-M
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Application
用作烯醇三氟甲磺酸酯与乙烯基硼酸进行羰化 Suzuki 偶联中的碱。
可作为反应物用于：
- 制备合成氟烯丙基化合物过程中的合成砌块
- 在中性pH下和缓冲的有机-水混合溶液中，通过水解烷基甲硅烷基醚来合成醇
- 炔基碘鎓盐的亲核氟化，以形成氟代乙烯基化合物
- 亲核芳香取代（SNAr）反应
用于成功合成单晶Dion-Jacobson相CsLaTa2O7，其在光催化和超导性方面具有应用。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2
target_organs
Kidney,Adrenal gland
supp_hazards
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
European Journal of Organic Chemistry, 2152-2152 (2007)
Jonathan L Sessler et al.
Journal of the American Chemical Society, 130(39), 13162-13166 (2008-09-09)
An ion-pair receptor, 1, containing both cation- and anion-recognizing sites, has been synthesized and characterized. Single-crystal X-ray diffraction structural studies and (1)H NMR spectroscopic analyses confirmed that 1 forms stable 1:1 complexes with CsF in solution and in the solid
Katsushi Kitahara et al.
Organic letters, 10(11), 2259-2261 (2008-05-01)
A variety of oximes were synthesized from the corresponding alcohols, alkyl halides, or alkyl sulfonates without using external oxidants. With this simple two-step procedure involving substitution with readily available TsNHOTBS and subsequent treatment with CsF, a range of oximes were
B Tabakoff et al.
The New England journal of medicine, 318(3), 134-139 (1988-01-21)
Blood platelets are an accessible tissue that reflects the activity of many enzymes found in the brain. To investigate the possible effect on such enzymes of long-term consumption of large quantities of ethanol, we assayed the activities of two enzymes
Shengcai Zheng et al.
Chemical communications (Cambridge, England), 47(24), 6969-6971 (2011-05-20)
One pot asymmetrical double allylations of sodium sulfide catalyzed by an iridium complex along with a combination of caesium fluoride and water in dichloromethane have been realized and the double allylation products with two C-S bond chiral centers were obtained
商品
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 255718-10G | 04061826016831 |
| 255718-50G | 04061833595909 |
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