255831
氯化锗(IV)
99.999% trace metals basis
别名:
四氯化锗
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关于此项目
线性分子式:
GeCl4
化学文摘社编号:
分子量:
214.45
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-116-7
MDL number:
Assay:
99.999% trace metals basis
Form:
liquid
InChI key
IEXRMSFAVATTJX-UHFFFAOYSA-N
InChI
1S/Cl4Ge/c1-5(2,3)4
SMILES string
Cl[Ge](Cl)(Cl)Cl
vapor pressure
76 mmHg ( 20 °C)
assay
99.999% trace metals basis
form
liquid
reaction suitability
reagent type: catalyst
core: germanium
impurities
≤15.0 ppm Trace Metal Analysis
bp
83 °C (lit.)
mp
−49.5 °C (lit.)
density
1.88 g/mL at 25 °C
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Application
用于通过微波法制备 Ge2Cl6，这是一种无色结晶物质，用于低价锗化合物的深入研究。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Does not sustain combustion.
flash_point_c
Does not sustain combustion.
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Ian R. Beattie et al.
Inorganic chemistry, 37(23), 6032-6034 (2001-10-24)
The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is very moisture-sensitive and decomposes readily in vacuo to give GeCl(4)
Murat Kaya et al.
Talanta, 84(1), 122-126 (2011-02-15)
A new chloride generation system was designed for the direct, sensitive, rapid and accurate determination of the total germanium in complex matrices. It was aimed to improve the detection limit of chloride generation technique by increasing the vapor pressure of
Zehui Zhang et al.
ChemSusChem, 4(1), 131-138 (2011-01-13)
Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly process. Monosaccharides D-fructose and D-glucose, disaccharides sucrose and maltose, and even the polysaccharide cellulose were
Amit Pratap Singh et al.
Journal of the American Chemical Society, 134(10), 4998-5003 (2012-02-15)
Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl(+)) and anionic (MCl(3)(-)) species
Sung Ki Cho et al.
Journal of the American Chemical Society, 137(20), 6638-6642 (2015-05-06)
We demonstrate the feasibility of semiconductor deposition via the electrochemical reduction of gaseous precursors by the use of an anhydrous proton-conducting membrane, the solid acid CsHSO4, at 165 °C. This membrane electrode assembly was operated within the oxidation of hydrogen
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