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Merck
CN

255831

氯化锗(IV)

99.999% trace metals basis

别名:

四氯化锗

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关于此项目

线性分子式:
GeCl4
化学文摘社编号:
分子量:
214.45
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-116-7
MDL number:
Assay:
99.999% trace metals basis
Form:
liquid
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vapor pressure

76 mmHg ( 20 °C)

assay

99.999% trace metals basis

form

liquid

reaction suitability

reagent type: catalyst
core: germanium

impurities

≤15.0 ppm Trace Metal Analysis

bp

83 °C (lit.)

mp

−49.5 °C (lit.)

density

1.88 g/mL at 25 °C

SMILES string

Cl[Ge](Cl)(Cl)Cl

InChI

1S/Cl4Ge/c1-5(2,3)4

InChI key

IEXRMSFAVATTJX-UHFFFAOYSA-N

Application

用于通过微波法制备 Ge2Cl6,这是一种无色结晶物质,用于低价锗化合物的深入研究。


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signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Does not sustain combustion.

flash_point_c

Does not sustain combustion.

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Ian R. Beattie et al.
Inorganic chemistry, 37(23), 6032-6034 (2001-10-24)
The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is very moisture-sensitive and decomposes readily in vacuo to give GeCl(4)
Murat Kaya et al.
Talanta, 84(1), 122-126 (2011-02-15)
A new chloride generation system was designed for the direct, sensitive, rapid and accurate determination of the total germanium in complex matrices. It was aimed to improve the detection limit of chloride generation technique by increasing the vapor pressure of
Zehui Zhang et al.
ChemSusChem, 4(1), 131-138 (2011-01-13)
Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly process. Monosaccharides D-fructose and D-glucose, disaccharides sucrose and maltose, and even the polysaccharide cellulose were



全球贸易项目编号

货号GTIN
255831-1G04061838084125
255831-10G04061838069627