255920
1,1′-(偶氮二羰基)二哌啶
99%
别名:
1,1′-偶氮双（N，N-五亚甲基甲酰胺）, ADD, NSC 356027, SR 4077, 偶氮二甲酰二哌啶
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关于此项目
经验公式（希尔记法）:
C12H20N4O2
化学文摘社编号:
分子量:
252.31
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
261917
Assay:
99%
Form:
solid
InChI
1S/C12H20N4O2/c17-11(15-7-3-1-4-8-15)13-14-12(18)16-9-5-2-6-10-16/h1-10H2/b14-13+
SMILES string
O=C(\N=N\C(=O)N1CCCCC1)N2CCCCC2
InChI key
OQJBFFCUFALWQL-BUHFOSPRSA-N
assay
99%
form
solid
mp
134-136 °C (lit.)
functional group
azo
Quality Level
Application
制备用反应物：
反应物用于：
- 多氟烷基化三吡唑甲烷配体
- 通过 Mitsunobu 糖基化的 (-)-潮霉素 A
- 通过 Mitsunobu 反应光学活性 α,α-二取代氨基酸
- 通过 [2 + 2] 环加成反应合成叠氮-β-内酰胺类
- 糖基二硫化物
- 吡啶醚类 PPAR 激动剂
- 组合新糖肽合成的 S-糖基氨基酸构件
- 组胺 H3 受体拮抗剂
反应物用于：
- Mitsunobu 翻转反应
广泛用于 Mitsunobu 反应的试剂
用于研究芳基硼酸通过铜催化加成得到偶氮二甲酸衍生物，从而生成芳基取代酰肼的反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Tetrahedron Letters, 34, 1639-1639 (1993)
Dougherty, J.M.; et al.
Tetrahedron, 61, 6218-6218 (2005)
Takeshi Uemura et al.
The Journal of organic chemistry, 70(21), 8631-8634 (2005-10-08)
The addition of arylboronic acids 1 to azodicarboxylates 2 in the presence of a catalytic amount of a copper salt under mild reaction conditions gives aryl-substituted hydrazines 3 in high yields. The reaction is tolerant of a wide variety of
M A Baker et al.
Radiation research, 113(2), 346-355 (1988-02-01)
The mechanism of radiosensitization by diazenedicarboxylic acid bis(N),N-piperidide (SR 4077), a less toxic analog of diamide, was studied using Chinese hamster ovary cells. SR 4077 gave an average SER of 1.58 for postirradiation incubations of 0.5, 1.0, or 2.0 h.
E A Bump et al.
International journal of radiation oncology, biology, physics, 12(8), 1533-1535 (1986-08-01)
Several analogs of the glutathione (GSH) oxidizing reagent diamide [diazenedicarboxylic acid bis(N,N'-diethylamide)] were tested as radiosensitizers of aerobic cells. In general, radiosensitization correlates with the rate of reaction with cellular reducing agents and occurs only when the reductive capacity of
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