255920
1,1′-(偶氮二羰基)二哌啶
99%
别名:
1,1′-偶氮双（N，N-五亚甲基甲酰胺）, ADD, NSC 356027, SR 4077, 偶氮二甲酰二哌啶
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关于此项目
经验公式（希尔记法）:
C12H20N4O2
化学文摘社编号:
分子量:
252.31
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
261917
产品名称
1,1′-(偶氮二羰基)二哌啶, 99%
InChI
1S/C12H20N4O2/c17-11(15-7-3-1-4-8-15)13-14-12(18)16-9-5-2-6-10-16/h1-10H2/b14-13+
SMILES string
O=C(\N=N\C(=O)N1CCCCC1)N2CCCCC2
InChI key
OQJBFFCUFALWQL-BUHFOSPRSA-N
assay
99%
form
solid
mp
134-136 °C (lit.)
functional group
azo
Quality Level
Application
制备用反应物：
反应物用于：
- 多氟烷基化三吡唑甲烷配体
- 通过 Mitsunobu 糖基化的 (-)-潮霉素 A
- 通过 Mitsunobu 反应光学活性 α,α-二取代氨基酸
- 通过 [2 + 2] 环加成反应合成叠氮-β-内酰胺类
- 糖基二硫化物
- 吡啶醚类 PPAR 激动剂
- 组合新糖肽合成的 S-糖基氨基酸构件
- 组胺 H3 受体拮抗剂
反应物用于：
- Mitsunobu 翻转反应
广泛用于 Mitsunobu 反应的试剂
用于研究芳基硼酸通过铜催化加成得到偶氮二甲酸衍生物，从而生成芳基取代酰肼的反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
E A Bump et al.
International journal of radiation oncology, biology, physics, 29(2), 249-253 (1994-05-15)
To determine whether biological effects of radiation, such as apoptosis, that differ from classical clonogenic cell killing, can be modified with agents that would not be expected to modify classical clonogenic cell killing. This would expand the range of potential
Hiroki Sato et al.
Bioorganic & medicinal chemistry, 10(5), 1595-1610 (2002-03-12)
Structure--activity relationship studies of 1beta-methyl-2-[(3S,5R)-5-(4-aminomethylphenyl)pyrrolidin-3-ylthio]carbapenems, especially those pertaining to the relationship between antibacterial activity and side-chain structure were conducted. These studies suggested that the trans-(3S,5R)-5-phenylpyrrolidin-3-ylthio side-chain and the aminomethyl group at the 4-position of the phenyl ring play a key
E A Bump et al.
International journal of radiation oncology, biology, physics, 12(8), 1533-1535 (1986-08-01)
Several analogs of the glutathione (GSH) oxidizing reagent diamide [diazenedicarboxylic acid bis(N,N'-diethylamide)] were tested as radiosensitizers of aerobic cells. In general, radiosensitization correlates with the rate of reaction with cellular reducing agents and occurs only when the reductive capacity of
M A Baker et al.
Radiation research, 113(2), 346-355 (1988-02-01)
The mechanism of radiosensitization by diazenedicarboxylic acid bis(N),N-piperidide (SR 4077), a less toxic analog of diamide, was studied using Chinese hamster ovary cells. SR 4077 gave an average SER of 1.58 for postirradiation incubations of 0.5, 1.0, or 2.0 h.
Dougherty, J.M.; et al.
Tetrahedron, 61, 6218-6218 (2005)
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