257885
三甲基硅基环戊二烯，异构体混合物
别名:
NSC 176274
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关于此项目
经验公式（希尔记法）:
C8H14Si
化学文摘社编号:
分子量:
138.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Form:
liquid
InChI
1S/C8H14Si/c1-9(2,3)8-6-4-5-7-8/h4-8H,1-3H3
SMILES string
C[Si](C)(C)C1C=CC=C1
InChI key
VMFHCJPMKUTMMQ-UHFFFAOYSA-N
form
liquid
refractive index
n20/D 1.471 (lit.)
bp
138-140 °C (lit.)
density
0.833 g/mL at 25 °C (lit.)
storage temp.
−20°C
Quality Level
General description
Trimethylsilyl cyclopentadiene reacts with ruthenium trichloride in alcohol solvent to yield ruthenocene.
Application
Reactant involved in:
- Diels-Alder reactions
- Synthesis of ring-functionalized molybdenocene complexes
- Allyl isomerization
- Aromatization of C5 rings
- Synthesis of N-hydroxyindoles via nucleophilic addition
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Multiple desilylation of silylated cyclopentadienes promoted by ionic ruthenium and rhodium halides.
Winter CH, et al.
Inorganic Chemistry, 32(17), 3654-3659 (1993)
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