258202
四氯化铪
98%
别名:
Hafnium tetrachloride, Tetrachlorohafnium
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关于此项目
线性分子式:
HfCl4
CAS Number:
分子量:
320.30
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
蒸汽压
1 mmHg ( 190 °C)
质量水平
方案
98%
表单
powder
反应适用性
core: hafnium
mp
432 °C (lit.)
溶解性
H2O: decomposes(lit.)
SMILES字符串
Cl[Hf](Cl)(Cl)Cl
InChI
1S/4ClH.Hf/h4*1H;/q;;;;+4/p-4
InChI key
PDPJQWYGJJBYLF-UHFFFAOYSA-J
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一般描述
氯化铪，又名四氯化铪，常用作前体生产铪金属和各种铪化合物。还用作某些有机合成反应的催化剂。因其反应性和湿度敏感性，氯化铪通常在惰性环境中处理。
应用
氯化铪用处：
- 作为前体合成磷酸铪锂，因其高离子导电性和化学稳定性而用作锂电池的固态电解质材料。
- 作为催化剂用于各种羰基化合物（包括醛和酮）的缩醛化反应。
- 作为催化剂用于羧酸与醇的直接酯化缩合反应。
- 作为锂和钠离子电池的高容量正极材料。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Direct condensation of carboxylic acids with alcohols catalyzed by hafnium (IV) salts.
Ishihara K, et al.
Science, 290.5494, 1140-1142 (2000)
Lutz Ackermann et al.
Organic & biomolecular chemistry, 5(12), 1975-1978 (2007-06-07)
Two distinct economical catalysts for intramolecular hydroaminations of electronically unactivated alkenes with basic amines are described, which are based on (a) group 4 metal halides under basic reaction conditions or (b) Brønsted-acid organocatalysts.
Guoguang Liu et al.
Biomacromolecules, 9(3), 949-953 (2008-02-15)
The feasibility of a previously established method based on ozonolysis and hydrogenation reactions for the production of 9-hydroxynonanoic acid from oleic acid has been demonstrated. Metal catalyzed lactonization conditions have been used to convert 9-hydroxynonanoic acid into 1,11-dioxacycloicosane-2,12-dione, which is
Visualization of the cytoskeletal elements in tissue culture cells by bloc-staining with hafnium chloride after rapid freezing and freeze-substitution fixation.
T Hatae et al.
Journal of electron microscopy, 33(2), 186-190 (1984-01-01)
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