Merck
CN

258784

Sigma-Aldrich

粪卟啉 I 二盐酸盐

synthetic

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别名:
3,8,13,18-四甲基-21H,23H-卟吩-2,7,12,17-四丙酸 二盐酸盐
经验公式(希尔记法):
C36H38N4O8 · 2HCl
CAS号:
分子量:
727.63
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

形式

solid

反应适用性

core: porphyrin
reagent type: catalyst

λmax

395 nm

SMILES字符串

Cl.Cl.Cc1c(CCC(O)=O)c2cc3[nH]c(cc4nc(cc5[nH]c(cc1n2)c(CCC(O)=O)c5C)c(CCC(O)=O)c4C)c(CCC(O)=O)c3C

InChI

1S/C36H38N4O8.2ClH/c1-17-21(5-9-33(41)42)29-14-26-19(3)23(7-11-35(45)46)31(39-26)16-28-20(4)24(8-12-36(47)48)32(40-28)15-27-18(2)22(6-10-34(43)44)30(38-27)13-25(17)37-29;;/h13-16,37,40H,5-12H2,1-4H3,(H,41,42)(H,43,44)(H,45,46)(H,47,48);2*1H/b25-13-,26-14-,27-15-,28-16-,29-14-,30-13-,31-16-,32-15-;;

InChI key

XROPZSRTTZKNQB-ARSPAUKVSA-N

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一般描述

粪卟啉二盐酸化物是一种卟啉,可作为起始原料合成单官能的磷光金属卟啉标记试剂。

应用

产品适配我们的光反应器系列:包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Preparation of monofunctional and phosphorescent palladium (II) and platinum (II) coproporphyrin labeling reagents
Journal of Porphyrins and Phthalocyanines, 5(10), 735-741 (2001)
Rita Giovannetti et al.
Talanta, 63(4), 857-864 (2008-10-31)
The reaction of 3,8,13,18-tetramethyl-21H,23H-porphine-2,7,12,17-tetrapropionic acid or coproporphyrin-I (CPI) with the elements of 11 group have been studied. CPI is an anionic porphyrin that slowly reacts with copper ion to form Cu(II)CPI and with silver ions to form Ag(II)CPI, Ag(III)CPI complexes
R Giovannetti et al.
Talanta, 42(12), 1913-1918 (1995-12-01)
The reagent 3,8,13,18-tetramethyl-21H,23H-porphine-2,7,12,17-tetrapropionic acid or coproporphyrin-I (CPI) was used for the spectrophotometric determination of copper(II) and cobalt(II) in the presence of pyridine and imidazole catalysts. Optimum conditions were investigated and the methods were applied to the determination of parts per
Krzysztof Kilian et al.
Talanta, 60(4), 669-678 (2008-10-31)
The reaction of 5,10,15,20-tetrakis(4-carboxylphenyl)porphyrin (TCPP) with Cd(II), Pb(II), Hg(II) and Zn(II) was studied spectrophotometrically and kinetics, equilibrium constants as well as photodecomposition of complexes were determined. It was verified that these metal ions with large radius accelerate the incorporation reaction
R Giovannetti et al.
Talanta, 46(5), 977-984 (2008-10-31)
The reaction of 3,8,13,18-tetramethyl-21H,23H-porphine-2,7,12,17-tetrapropionic acid or coproporphyrin-I (CPI) with mercury(II) was studied spectrophotometrically, and kinetic and equilibrium constants were determined; the influence of temperature on the reaction rate was also studied. It was verified that mercury(II) accelerates the incorporation reaction

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