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Merck
CN

259160

1,4,8,11-四氮杂环十四烷

98% (GC)

别名:

1,4,8,11-四氮环十四烷

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关于此项目

经验公式（希尔记法）:
C10H24N4
化学文摘社编号:
295-37-4
分子量:
200.32
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
24855689
EC Number:
206-039-1
Beilstein/REAXYS Number:
111811
MDL number:
MFCD00005105

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产品名称

1,4,8,11-四氮杂环十四烷, 98% (GC)

InChI key

MDAXKAUIABOHTD-UHFFFAOYSA-N

InChI

1S/C10H24N4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h11-14H,1-10H2

SMILES string

C1CNCCNCCCNCCNC1

assay

98% (GC)

mp

184-186 °C (lit.)

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相关类别

Application

1,4,8,11-四氮杂环十四烷(cyclam)可作为配体用于合成：
  • 氰化物桥联FeIII-CuII配合物。
  • 具有抗菌性的芬那酸锌配合物[Zn(cyclam)(fen)2]，fen=芬那酸。
  • Zn(II)氟芬那酸
  • (flu)配合物，[Zn(cyclam)(flu)2]。
  • 多金属氧酸盐-有机金属框架，如[{Cu(cyclam)}3(W7O24)].15.5.H2O。

General description

1,4,8,11-四氮杂环十四烷是一种氮杂大环，可形成比开链配体更稳定的金属配合物。

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX6563
MKCX1975
MKCX0407
MKCX0406
MKCX0405

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Jaeheung Cho et al.
Accounts of chemical research, 45(8), 1321-1330 (2012-05-23)
Metalloenzymes activate dioxygen to carry out a variety of biological reactions, including the biotransformation of naturally occurring molecules, oxidative metabolism of xenobiotics, and oxidative phosphorylation. The dioxygen activation at the catalytic sites of the enzymes occurs through several steps, such
Riccardo Ferdani et al.
Dalton transactions (Cambridge, England : 2003), 41(7), 1938-1950 (2011-12-16)
A new class of cross-bridged cyclam-based macrocycles featuring phosphonate pendant groups has been developed. 1,4,8,11-tetraazacyclotetradecane-1,8-di(methanephosphonic acid) (CB-TE2P, 1) and 1,4,8,11-tetraazacyclotetradecane-1-(methanephosphonic acid)-8-(methanecarboxylic acid) (CB-TE1A1P, 2) have been synthesized and have been shown to readily form neutral copper(II) complexes at room temperature
Synthesis, characterization, DNA binding, topoisomerase I inhibition and antimicrobial activity of four novel zinc (II) fenamates.
Smolkova R, et al.
Polyhedron, 141(17), 230-238 (2018)
A serials of sandwich-like trinuclear and one-dimensional chain cyanide-bridged iron (III)-copper (II) complexes: Syntheses, crystal structures and magnetic properties.
Shi J, et al.
Journal of Solid State Chemistry, 260(17), 59-66 (2018)
Luis G Alves et al.
Dalton transactions (Cambridge, England : 2003), 41(47), 14288-14298 (2012-10-09)
Novel Bn(2)Cyclam-based zirconium complexes of the type (Bn(2)Cyclam)Zr(X)(X') (3, X = X' = OPh; 4, X = X' = SPh; 5, X = Cl, X' = O(i)Pr) were synthesized in good yields via metathesis routes involving the reaction of the
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