259160
1,4,8,11-四氮杂环十四烷
98% (GC)
别名:
1,4,8,11-四氮环十四烷
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关于此项目
经验公式（希尔记法）:
C10H24N4
化学文摘社编号:
分子量:
200.32
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-039-1
Beilstein/REAXYS Number:
111811
MDL number:
assay
98% (GC)
mp
184-186 °C (lit.)
SMILES string
C1CNCCNCCCNCCNC1
InChI
1S/C10H24N4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h11-14H,1-10H2
InChI key
MDAXKAUIABOHTD-UHFFFAOYSA-N
General description
1,4,8,11-四氮杂环十四烷是一种氮杂大环，可形成比开链配体更稳定的金属配合物。
Application
1,4,8,11-四氮杂环十四烷(cyclam)可作为配体用于合成：
- 氰化物桥联FeIII-CuII配合物。
- 具有抗菌性的芬那酸锌配合物[Zn(cyclam)(fen)2]，fen=芬那酸。
- Zn(II)氟芬那酸
- (flu)配合物，[Zn(cyclam)(flu)2]。
- 多金属氧酸盐-有机金属框架，如[{Cu(cyclam)}3(W7O24)].15.5.H2O。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
实验方案
We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.
Abir El Majzoub et al.
Inorganic chemistry, 50(9), 4029-4038 (2011-04-12)
The coordination properties and the photophysical response of a new cyclam fluorescent probe for Zn(II), [L1H: 1-(benzimidazol-2-ylmethyl]-1,4, 8,11-tetraazacyclotetradecane] toward Cu(II), Zn(II), and Cd(II) are reported. The stability constants of the corresponding complexes were determined by means of potentiometric measurements in
Cyclam (1,4,8,11-tetraazacyclotetradecane) with one methylphosphonate pendant arm: a new ligand for selective copper (II) binding.
F?zerova S, et al.
Dalton Transactions, 2908-2915 (2005)
Apurba Kalita et al.
Inorganic chemistry, 50(23), 11868-11876 (2011-11-02)
The nitric oxide reactivity of two copper(II) complexes, 1 and 2 with ligands L(1) and L(2), respectively, [L(1) = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, L(2) = 5,5,7-trimethyl-[1,4]-diazepane] have been studied. The copper(II) center in complex 1 was found to be unreactive toward nitric oxide
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 259160-5G | 04061826075227 |
| 259160-1G | 04061826075210 |