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Merck
CN

259616

4-氯苯甲酰肼

98%

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关于此项目

线性分子式:
ClC6H4CONHNH2
化学文摘社编号:
分子量:
170.60
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-632-0
Beilstein/REAXYS Number:
511154
MDL number:
Assay:
98%
Form:
solid
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Quality Level

assay

98%

form

solid

mp

162-165 °C (lit.)

functional group

amine, chloro, hydrazine

SMILES string

NNC(=O)c1ccc(Cl)cc1

InChI

1S/C7H7ClN2O/c8-6-3-1-5(2-4-6)7(11)10-9/h1-4H,9H2,(H,10,11)

InChI key

PKBGHORNUFQAAW-UHFFFAOYSA-N

General description

Effect of acidic catalyst on the reaction of 4-chlorobenzhydrazide and β-naphthol in water has been investigated.

Application

4-Chlorobenzhydrazide has been used in preparation of:
  • rod-shaped mesogenic hydrazide derivatives via Schotten-Baumann reaction with 4-n-alkoxybenzoyl chloride
  • 4-methoxybenzaldehyde-4-chlorophenyl-1-carbonyl hydrazone
  • 4-hydroxybenzaldehyde-4-chlorophenyl-1-carbonylhydrazone
  • 2-nitrobenzaldehyde-4-chlorophenyl-1-carbonylhydrazone
  • benzaldehyde-4-chlorophenyl-1-carbonylhydrazone


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

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Jagvir Singh et al.
Bioinorganic chemistry and applications, 2012, 104549-104549 (2012-11-06)
N-substituted pyridine hydrazide (pyridine-2-carbonyl chloride and 4-chloro-benzoic acid hydrazide) undergoes hydrazide formation of the iminic carbon nitrogen double bond through its reaction with cobalt(II), nickel(II), and copper(II) metal salts in ethanol which are reported and characterized based on elemental analyses
Minoo Dabiri et al.
Bioorganic & medicinal chemistry letters, 18(1), 436-438 (2007-12-07)
Alkyl- or aryl-14H-dibenzo[a,j]xanthene derivatives are synthesized efficiently by the reaction of beta-naphthol and aliphatic and aromatic aldehydes in the presence of KAl(SO4)2 x 12 H2O (alum) under aqueous condition at 100 degrees C. Different types of aromatic and aliphatic aldehydes
Synthesis of benzaldehyde substituted phenyl carbonyl hydrazones and their formylation using Vilsmeier-Haack reaction.
Rajput AP and Rajput AS.
International Journal of PharmTech Research, 1(4), 1605-1611 (2009)



全球贸易项目编号

货号GTIN
259616-25G04061831838213
259616-5G04061826075371