260630
叔丁基异氰酸酯
98%
别名:
1,1-二甲基乙基异氰化物, 1-叔丁基异腈, 2-异氰基-2-甲基丙烷, 叔丁基异腈
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关于此项目
线性分子式:
(CH3)3CNC
化学文摘社编号:
分子量:
83.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
230-553-5
Beilstein/REAXYS Number:
1903156
MDL number:
Assay:
98%
Form:
liquid
InChI key
FAGLEPBREOXSAC-UHFFFAOYSA-N
InChI
1S/C5H9N/c1-5(2,3)6-4/h1-3H3
SMILES string
CC(C)(C)[N+]#[C-]
assay
98%
form
liquid
Quality Level
refractive index
n20/D 1.376 (lit.)
bp
91 °C (lit.)
density
0.735 g/mL at 25 °C (lit.)
functional group
amine, isonitrile
General description
据报道， 叔丁基异氰酸酯在锗（100）表面形成碳配价键。它还与金属形成络合物，并插入金属-碳键中，形成亚氨基酰基。
Application
叔丁基异氰酸酯被用于合成 香豆素、4H-色烯 和 异恶唑啉。它还被用于捕获2-环亚丙基-1,3-二酮。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
28.4 °F - closed cup
flash_point_c
-2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Issa Yavari et al.
Molecular diversity, 8(4), 431-435 (2004-12-23)
The adduct produced in the reaction between tert-butyl isocyanide and dialkyl acetylenedicarboxylates was trapped by alkyl 2-arylamino-2-oxo-acetates. When the aryl group is 2-methyl-6-nitrophenyl or 2,6-di-isopropylphenyl, the product exists as two stable rotamers at room temperature as a result of restricted
Xiao Jiang et al.
Organic letters, 16(13), 3492-3495 (2014-06-24)
A novel palladium-catalyzed formylation of aryl halides with isocyanide in the presence of Et3SiH has been demonstrated, which provides a strategy toward important aldehydes with moderate to excellent yield. The advantage of this reaction includes milder conditions, convenient operation, lower
Bonggeun Shong et al.
Journal of the American Chemical Society, 139(25), 8758-8765 (2017-06-01)
Reactions of the (100) surfaces of Ge and Si with organic molecules have been generally understood within the concept of "dimers" formed by the 2 × 1 surface reconstruction. In this work, the adsorption of tert-butyl isocyanide on the Ge(100)-2
David Sýkora et al.
Journal of separation science, 43(22), 4178-4190 (2020-09-21)
Eight different stationary phases based on two aminopropyl silicas of different brands suitable for multimodal chromatography applications have been prepared by a four-component Ugi reaction. The intention was to synthesize stationary phases significantly differing in their properties hereby demonstrating flexibility
Habib Nasri et al.
Inorganic chemistry, 43(9), 2932-2942 (2004-04-27)
The addition of the strongly pi-bonding ligands CO or tert-butyl isocyanide to the low-spin five-coordinate iron(II) nitrite species [Fe(TpivPP)(NO2)]- (TpivPP = picket fence porphyrin) gives two new six-coordinate species [Fe(TpivPP)(NO2)(CO)]- and [Fe(TpivPP)(NO2)(t-BuNC)]-. These species have been characterized by single-crystal structure
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