260630
叔丁基异氰酸酯
98%
别名:
1,1-二甲基乙基异氰化物, 1-叔丁基异腈, 2-异氰基-2-甲基丙烷, 叔丁基异腈
质量水平
方案
98%
表单
liquid
折射率
n20/D 1.376 (lit.)
沸点
91 °C (lit.)
密度
0.735 g/mL at 25 °C (lit.)
官能团
amine
isonitrile
SMILES字符串
CC(C)(C)[N+]#[C-]
InChI
1S/C5H9N/c1-5(2,3)6-4/h1-3H3
InChI key
FAGLEPBREOXSAC-UHFFFAOYSA-N
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一般描述
据报道， 叔丁基异氰酸酯在锗（100）表面形成碳配价键。它还与金属形成络合物，并插入金属-碳键中，形成亚氨基酰基。
应用
叔丁基异氰酸酯被用于合成 香豆素、4H-色烯 和 异恶唑啉。它还被用于捕获2-环亚丙基-1,3-二酮。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Inhalation - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
28.4 °F - closed cup
闪点(°C)
-2 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Synthesis, 995-995 (1990)
Bonggeun Shong et al.
Journal of the American Chemical Society, 136(16), 5848-5851 (2014-04-15)
Carbon dative bond formation between an organic molecule and a semiconductor surface is reported here for the first time. Our studies show that the adsorption of tert-butyl isocyanide on the (100) surface of germanium, measured using Fourier transform infrared spectroscopy
Bonggeun Shong et al.
Journal of the American Chemical Society, 139(25), 8758-8765 (2017-06-01)
Reactions of the (100) surfaces of Ge and Si with organic molecules have been generally understood within the concept of "dimers" formed by the 2 × 1 surface reconstruction. In this work, the adsorption of tert-butyl isocyanide on the Ge(100)-2
David Sýkora et al.
Journal of separation science, 43(22), 4178-4190 (2020-09-21)
Eight different stationary phases based on two aminopropyl silicas of different brands suitable for multimodal chromatography applications have been prepared by a four-component Ugi reaction. The intention was to synthesize stationary phases significantly differing in their properties hereby demonstrating flexibility
Xiao Jiang et al.
Organic letters, 16(13), 3492-3495 (2014-06-24)
A novel palladium-catalyzed formylation of aryl halides with isocyanide in the presence of Et3SiH has been demonstrated, which provides a strategy toward important aldehydes with moderate to excellent yield. The advantage of this reaction includes milder conditions, convenient operation, lower
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