260851
2-溴茴香硫醚
97%
别名:
2-溴苯甲硫醚
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关于此项目
线性分子式:
BrC6H4SCH3
化学文摘社编号:
分子量:
203.10
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
243-183-4
MDL number:
Assay:
97%
Form:
liquid
InChI key
ALAQDUSTXPEHMH-UHFFFAOYSA-N
InChI
1S/C7H7BrS/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3
SMILES string
CSc1ccccc1Br
assay
97%
form
liquid
refractive index
n20/D 1.633 (lit.)
bp
145-146 °C/27 mmHg (lit.)
mp
−24 °C (lit.)
density
1.522 g/mL at 25 °C (lit.)
functional group
bromo, thioether
Quality Level
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Application
2-Bromothioanisole has been used in the preparation of:
- thioether-methyleneborane (PhSCH2B (C6F5)2)2
- 1-dimesitylboryl-2-methylthio-benzene
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
The thioether-methyleneborane (PhSCH2B (C6F5) 2) 2: synthesis and reactivity with donors and alkynes.
Tanur CA and Stephan DW.
Organometallics, 30(13), 3652-3657 (2011)
Youngmin Kim et al.
Angewandte Chemie (International ed. in English), 48(27), 4957-4960 (2009-06-06)
Going fishing! The sulfonium borane [1](+) complexes cyanide in pure water at the maximum allowable concentration of 50 ppb recommended by the European Union. The high cyanide ion affinity displayed by this compound arises from favorable Coulombic effects augmented by
Isolation of S-(bromophenyl)cysteine isomers from liver proteins of bromobenzene-treated rats.
P E Weller et al.
Chemical research in toxicology, 4(1), 17-20 (1991-01-01)
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