261483
N,N-二甲基乙酰胺二甲基乙缩醛
90%
别名:
1,1-二甲氧基-N,N-二甲基乙胺
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关于此项目
线性分子式:
CH3C(OCH3)2N(CH3)2
化学文摘社编号:
分子量:
133.19
Beilstein:
1420865
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
90%
表单
liquid
折射率
n20/D 1.411 (lit.)
沸点
118 °C (lit.)
密度
0.911 g/mL at 25 °C (lit.)
官能团
amine
ether
SMILES字符串
COC(C)(OC)N(C)C
InChI
1S/C6H15NO2/c1-6(8-4,9-5)7(2)3/h1-5H3
InChI key
FBZVZUSVGKOWHG-UHFFFAOYSA-N
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一般描述
已经研究了以光学活性反式3-戊烯-2-醇为底物时，N,N-二甲基乙酰胺二甲基乙缩醛的克莱森反应。
应用
N,N-二甲基乙酰胺二甲基乙缩醛已被用作：
- 用于制备嘧啶并[1,2-a][1,3,5]三嗪-6-酮的一碳插入合成单体
- 用于合成酰胺、二酰胺和杂环的试剂
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 2 - STOT SE 3
靶器官
Eyes,Central nervous system, Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
46.4 °F - closed cup
闪点(°C)
8 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Organic & biomolecular chemistry, 10(23), 4586-4596 (2012-05-15)
A novel thermal rearrangement, involving pyrimidine ring opening and subsequent ring closure leading to recyclization of the system, was identified in the reaction of (6-oxo-1,6-dihydropyrimidin-2-yl)guanidines 3 (where NR(1)R(2) = NH(2), NH alkyl, NH aralkyl, NHCH(2)Ph(R)) with triethyl orthoacetate, affording 4-substituted-2-methyl-6H-pyrimido[1,2-a][1,3,5]triazin-6-ones
Piotr Szustakiewicz et al.
Nanomaterials (Basel, Switzerland), 9(4) (2019-04-14)
In this study, we report a universal approach allowing the non-covalent deposition of gold nanoparticles on reduced graphene oxide surface in a controlled fashion. We used a modified Hummers method to obtain graphene oxide, which then underwent surficial functionalization with
Synthesis, 119-119 (1980)
The Journal of Organic Chemistry, 57, 7133-7133 (1992)
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