261920
1,2-双(二氯膦基)乙烷
97%
别名:
1,2-双(二氯磷基)-乙烷, 1,2-双(二氯磷氢基)-乙烷, 1,2-双(二氯膦基)乙烷
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关于此项目
线性分子式:
Cl2PCH2CH2PCl2
化学文摘社编号:
分子量:
231.81
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.588 (lit.)
沸点
70 °C/1 mmHg (lit.)
密度
1.536 g/mL at 25 °C (lit.)
官能团
phosphine
SMILES字符串
ClP(Cl)CCP(Cl)Cl
InChI
1S/C2H4Cl4P2/c3-7(4)1-2-8(5)6/h1-2H2
InChI key
SBWAJHLQMFBNIN-UHFFFAOYSA-N
一般描述
1,2-双(二氯磷基)-乙烷是一种有机磷化合物，通常作为前体与有机金属反应合成乙烯桥联双磷烷配体。
应用
1,2-双(二氯磷基)-乙烷可作为前体合成1,2-双(二氯膦酰基)-乙烷（ethylenebis(phosphonic dichloride)）。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Electron-Poor Olefin Polymerization Catalysts Based on Semi-Fluorinated Bis (phosphane) s
European Journal of Inorganic Chemistry, 2000(9), 2063-2070 (2000)
Cofactor-type inhibitors of inosine monophosphate dehydrogenase via modular approach: targeting the pyrophosphate binding sub-domain
Felczak K, et al.
Bioorganic & Medicinal Chemistry, 9(5), 1594-1605 (2011)
A convenient synthesis of 1, 2-bis (dichlorophosphino) ethane, 1, 2-bis (dimethylphosphino) ethane and 1, 2-bis (diethylphosphino) ethane
Burt RJ, et al.
Journal of Organometallic Chemistry, 182(2), 203-206 (1979)
Ruiyan Sun et al.
ChemSusChem, 12(14), 3278-3285 (2019-04-30)
Methyl formate was produced in one pot through the hydrogenation of CO2 to formic acid/formate followed by an esterification step. The route offers the possibility to integrate renewable energy into the fossil-based chemical value chain. In this work, a phosphine-polymer-anchored
相关内容
Phosphine Ligand Application Guide
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