261963
高铼酸 溶液
75-80 wt. % in H2O, liquid
别名:
四氧铼酸氢, 高铼酸氢
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关于此项目
线性分子式:
HReO4
化学文摘社编号:
分子量:
251.21
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
高铼酸 溶液, 75-80 wt. % in H2O
SMILES string
O[Re](=O)(=O)=O
InChI
1S/H2O.3O.Re/h1H2;;;;/q;;;;+1/p-1
InChI key
UGSFIVDHFJJCBJ-UHFFFAOYSA-M
form
liquid
reaction suitability
core: rhenium
reagent type: catalyst
concentration
75-80 wt. % in H2O
density
2.16 g/mL at 25 °C
Quality Level
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Application
- 高铼酸溶液（HReO4）可用于肟、酰胺和尿素的脱水。
- HReO4还可催化顺醛肟或反醛肟的共沸脱水生成相应的腈。
- 与叔胂结合，可为烯烃与过氧化氢的环氧化提供通用的催化体系。
它还用于制备高导电和超导的合成金属。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Rhenium catalysed epoxidations with hydrogen peroxide: tertiary arsines as effective cocatalysts.
van Vliet, Michiel CA et al.
Journal of the Chemical Society, 114(3), 377-380 (2000)
Inorg. Synth., 26, 386-386 (1989)
Alexiane Thevenet et al.
Dalton transactions (Cambridge, England : 2003), 50(5), 1620-1630 (2021-01-21)
The extraction of technetium, present in nitric acid medium as pertechnetate anion, is an issue in solvent extraction processes used to recover uranium and plutonium. In the present study, a complexing agent is added in the aqueous nitric acid solution
Rhenium (VII) Oxide.
eEROS (Encyclopedia of Reagents for Organic Synthesis), 114(16), 3109-3112 (2001)
Rhenium (VII) oxo complexes as extremely active catalysts in the dehydration of primary amides and aldoximes to nitriles.
Ishihara, Kazuaki et al.
Angewandte Chemie (International Edition in English), 114(16), 3109-3112 (2002)
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