26235
2-(3-氯丙基)-1,3-二噁戊环
≥97.0% (GC)
别名:
4-氯丁醛乙烯基乙缩醛
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关于此项目
经验公式（希尔记法）:
C6H11ClO2
化学文摘社编号:
分子量:
150.60
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1236588
Assay:
≥97.0% (GC)
Form:
liquid
Quality Level
assay
≥97.0% (GC)
form
liquid
refractive index
n20/D 1.453
bp
93-94 °C/12 mmHg (lit.)
density
1.142 g/mL at 20 °C (lit.)
functional group
chloro, ether
SMILES string
ClCCCC1OCCO1
InChI
1S/C6H11ClO2/c7-3-1-2-6-8-4-5-9-6/h6H,1-5H2
InChI key
ZBPUNVFDQXYNDY-UHFFFAOYSA-N
Application
2-(3-Chloropropyl)-1,3-dioxolane (2-(3′-chloropropyl)-1,3-dioxolane) is a masked γ-chlorobutyraldehyde and was used for the introduction of 3-(1,3-dioxolan-2-yl)propyl moiety. It was also used in the synthesis of:
- (±)-histrionicotoxin and (±)-histrionicotoxin 235A using a two-directional strategy
- 4-iodobutyraldehyde, 5-iodovaleraldehyde and 5-iodo-2-petanone
- corresponding phosphonate
Other Notes
含掩蔽的 γ-氯丁醛，用于引入 3-(1,3-二氧戊环-2-基)丙基部分；也可用于对应膦酸酯的制备和使用
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
R.E. Abbott et al.
The Journal of Organic Chemistry, 45, 5398-5398 (1980)
C.P. Forbes et al.
Journal of the Chemical Society. Perkin Transactions 1, 2353-2353 (1977)
A Nagy et al.
Proceedings of the National Academy of Sciences of the United States of America, 93(6), 2464-2469 (1996-03-19)
A convenient, high yield conversion of doxorubicin to 3'-deamino-3'-(2''-pyrroline-1''-yl)doxorubicin is described. This daunosamine-modified analog of doxorubicin is 500-1000 times more active in vitro than doxorubicin. The conversion is effected by using a 30-fold excess of 4-iodobutyraldehyde in anhydrous dimethylformamide. The
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 26235-25ML-F | 04061837014529 |
| 26235-5ML-F | 04061837014536 |