262501
5-溴-2-甲基-2-戊烯
97%
别名:
1-Bromo-4-methyl-3-pentene, 2-Methyl-5-bromo-2-pentene, 4-Methyl-3-pentenyl bromide, 5-Bromo-2-methyl-2-pentene, 5-Bromo-2-methylpent-2-ene, Homoprenyl bromide, Prenylmethyl bromide
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关于此项目
线性分子式:
BrCH2CH2CH=C(CH3)2
化学文摘社编号:
分子量:
163.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1735749
Assay:
97%
Form:
liquid
InChI
1S/C6H11Br/c1-6(2)4-3-5-7/h4H,3,5H2,1-2H3
SMILES string
C\C(C)=C\CCBr
InChI key
UNXURIHDFUQNOC-UHFFFAOYSA-N
assay
97%
form
liquid
refractive index
n20/D 1.476 (lit.)
bp
152-154 °C (lit.)
density
1.217 g/mL at 25 °C (lit.)
functional group
alkyl halide, bromo
storage temp.
2-8°C
Quality Level
Application
5-Bromo-2-methyl-2-pentene has been used in the synthesis of:
- geranlol-3-14C
- penifulvin A, a sesquiterpenoid with a novel dioxa-fenestrane structure
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
71.6 °F - closed cup
flash_point_c
22 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tanja Gaich et al.
Journal of the American Chemical Society, 131(2), 452-453 (2009-01-15)
Herein we report the first total synthesis of Penifulvin A, a sesquiterpenoid with a novel dioxa-fenestrane structure. Penifulvin A is a potent insecticide against the fall armyworm Spodoptera frugiperda which causes enormous damage in the US by consuming foliage of
Biosynthesis of the vinca alkaloids. The incorporation of geraniol-3-14C into catharanthine and vindoline.
Leete E and Ueda S.
Tetrahedron Letters, 7(40), 4915-4918 (1966)
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