262579
2-(溴甲基)四氢-2H-吡喃
98%
别名:
四氢-2H-吡喃-2-甲基溴
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关于此项目
经验公式（希尔记法）:
C6H11BrO
化学文摘社编号:
分子量:
179.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
98%
Form:
liquid
InChI
1S/C6H11BrO/c7-5-6-3-1-2-4-8-6/h6H,1-5H2
SMILES string
BrCC1CCCCO1
InChI key
MHNWCBOXPOLLIB-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.489 (lit.)
bp
153 °C (lit.)
mp
−59-−58 °C (lit.)
density
1.397 g/mL at 25 °C (lit.)
functional group
bromo, ether
Quality Level
General description
已研究2-(溴甲基)四氢-2H-吡喃和杂芳基三氟硼酸盐的交叉偶联反应。
Application
2-(溴甲基)四氢-2H-吡喃已用于制备碲化杂化，2-[(2-噻吩基碲基)甲基]四氢呋喃和[(2-噻吩基碲基)甲基]四氢-2H-吡喃。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Tellurated heterocycles, 2-[(2-thienyltelluro)methyl]tetrahydrofuran and [(2-thienyltelluro)methyl]tetrahydro-2H-pyran: Synthesis and complexation reactions with Pd(II), Pt(II), Hg(II), Ru(II) and Cu(I)
Bali S, et al.
Journal of Organometallic Chemistry, 691(18), 3788-3796 (2006)
Gary A Molander et al.
Organic letters, 12(24), 5783-5785 (2010-11-26)
A method for the cross-coupling of alkyl electrophiles with various potassium aryl- and heteroaryltrifluoroborates has been developed. Nearly stoichiometric amounts of organoboron species could be employed to cross-couple a large variety of challenging heteroaryl nucleophiles. Several functional groups were tolerated
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