263699
3-乙氧基丙烯腈，顺反式异构体混合物
97%
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关于此项目
线性分子式:
C2H5OCH=CHCN
化学文摘社编号:
分子量:
97.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
262-706-7
MDL number:
Assay:
97%
Form:
liquid
InChI key
HUPVIAINOSTNBJ-UHFFFAOYSA-N
InChI
1S/C5H7NO/c1-2-7-5-3-4-6/h3,5H,2H2,1H3
SMILES string
CCOC=CC#N
assay
97%
form
liquid
refractive index
n20/D 1.454 (lit.)
bp
90-91 °C/19 mmHg (lit.)
density
0.944 g/mL at 25 °C (lit.)
functional group
ether, nitrile
General description
Heck reaction of 3-ethoxyacrylonitrile with aryl bromides catalyzed by a tetraphosphine/palladium complex has been reported.
Application
3-Ethoxyacrylonitrile has been used in the preparation of (Z)-β-aminoacrylonitrile.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
179.6 °F - closed cup
flash_point_c
82 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Heck reactions of 2-substituted enol ethers with aryl bromides catalysed by a tetraphosphine/palladium complex.
Battace A, et al.
Tetrahedron Letters, 47(4), 459-462 (2006)
Sundeep Rayat et al.
Chemical research in toxicology, 18(8), 1211-1218 (2005-08-16)
A discussion of nitrosative deamination of cytosine 1 is presented that argues for the formation of 6 by diazotization of 1 to cytosinediazonium ion 2 and its electrostatic complex 3, dediazoniation to 4 <--> 5, and amide-bond cleavage to 6.
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