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Merck
CN

265640

Sigma-Aldrich

powder, <150 μm, 99.5% trace metals basis

别名:

Sn

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关于此项目

经验公式(希尔记法):
Sn
CAS Number:
分子量:
118.71
EC 号:
MDL编号:
UNSPSC代码:
11101716
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

99.5% trace metals basis

表单

powder

反应适用性

core: tin
reagent type: catalyst

电阻率

11 μΩ-cm, 20°C

粒径

<150 μm

沸点

2270 °C (lit.)

mp

231.9 °C (lit.)

密度

7.310 g/mL at 25 °C (lit.)

SMILES字符串

[Sn]

InChI

1S/Sn

InChI key

ATJFFYVFTNAWJD-UHFFFAOYSA-N

一般描述

锡是一种高效催化剂,用于乳酸缩聚合成聚乳酸。

应用

用HCl还原各种官能团;羰基化合物的立体选择性烯丙基化;原位生成锡烯醇化物用于定向羟醛反应。

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Improving lactic acid melt polycondensation: The role of co-catalyst
Marques DS, et al.
Journal of Applied Polymer Science, 128, 2145-2151 (2013)
P Olmedo et al.
Environment international, 59, 63-72 (2013-06-25)
Although fish intake has potential health benefits, the presence of metal contamination in seafood has raised public health concerns. In this study, levels of mercury, cadmium, lead, tin and arsenic have been determined in fresh, canned and frozen fish and
Lun Li et al.
Journal of the American Chemical Society, 135(4), 1213-1216 (2013-01-15)
Single-layer single-crystalline SnSe nanosheet with four-atomic thickness of ~1.0 nm and lateral size of ~300 nm is presented here by using a one-pot synthetic method. It is found that 1,10-phenanthroline plays an important role in determining the morphology of the
Shiyou Chen et al.
Advanced materials (Deerfield Beach, Fla.), 25(11), 1522-1539 (2013-02-13)
The kesterite-structured semiconductors Cu2ZnSnS4 and Cu2ZnSnSe4 are drawing considerable attention recently as the active layers in earth-abundant low-cost thin-film solar cells. The additional number of elements in these quaternary compounds, relative to binary and ternary semiconductors, results in increased flexibility
D B Shpakovsky et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14568-14582 (2012-10-12)
Four new organotin(IV) complexes of bis-(2,6-di-tert-butylphenol)tin(IV) dichloride [(tert-Bu-)(2)(HO-Ph)](2)SnCl(2) (1) with the heterocyclic thioamides 2-mercapto-pyrimidine (PMTH), 2-mercapto-4-methyl-pyrimidine (MPMTH), 2-mercapto-pyridine (PYTH) and 2-mercapto-benzothiazole (MBZTH), of formulae {[(tert-Bu-)(2)(HO-Ph)](2)Sn(PMT)(2)} (2), {[(tert-Bu-)(2)(HO-Ph)](2)Sn(MPMT)(2)} (3), {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(PYT)} (4) and {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(MBZT)} (5), have been synthesized and characterized by elemental

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