InChI
1S/Re
SMILES string
[ReH]
InChI key
WUAPFZMCVAUBPE-UHFFFAOYSA-N
assay
99.98% trace metals basis
form
foil
description
19.3 μΩ-cm, 20°C
thickness
0.25 mm
bp
5596 °C (lit.), 5627 °C (lit.)
mp
3180 °C (lit.)
density
21.02 g/cm3 (lit.)
Quality Level
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General description
铼(Rhenium)是极硬、耐磨损、抗腐蚀的稀有金属,原子序数较大。广泛用于催化领域和喷气发动机合金制备。
Application
铼可用作工作电极,用于电化学 析氢反应。
可用作钼-钛-锆(TZM)合金接头的添加剂,提高 拉伸强度。
也可作为催化剂,用于各种 加氢脱氧反应。
可用作钼-钛-锆(TZM)合金接头的添加剂,提高 拉伸强度。
也可作为催化剂,用于各种 加氢脱氧反应。
Preparation Note
3.3g = 25×25mm;13.2g = 50×50mm
存储类别
13 - Non Combustible Solids
wgk
nwg
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Cinzia Spagnul et al.
Journal of inorganic biochemistry, 122, 57-65 (2013-03-12)
The synthesis and characterization of two novel water soluble porphyrins with three meso pyridyl rings and one peripheral chelator - either a diethylenetriamine unit (4) or a bipyridyl fragment (8) - for binding to the {(99m)Tc(CO)3}(+) moiety is reported. In
Shalina C Bottorff et al.
Inorganic chemistry, 52(6), 2939-2950 (2013-03-06)
The viability of the Huisgen cycloaddition reaction for clickable radiopharmaceutical probes was explored with an alkyne-functionalized 2-[(pyridin-2-ylmethyl)amino]acetic acid (PMAA) ligand system, 3, and fac-[M(I)(OH2)3(CO)3](+) (M = Re, (99m)Tc). Two synthetic strategies, (1) click, then chelate and (2) chelate, then click
Yanfeng Jiang et al.
Journal of the American Chemical Society, 135(10), 4088-4102 (2013-02-07)
Diiodo Re(I) complexes [ReI2(NO)(PR3)2(L)] (3, L = H2O; 4 , L = H2; R = iPr a, Cy b) were prepared and found to exhibit in the presence of "hydrosilane/B(C6F5)3" co-catalytic systems excellent activities and longevities in the hydrogenation of
Jan Dietrich et al.
Inorganic chemistry, 52(3), 1248-1264 (2013-01-15)
New cationic metallo ligands L1-L3 based on bis(terpyridine) ruthenium(II) complexes decorated with differently substituted 2,2'-bipyridines attached via amide groups (5-NHCO-bpy, 4-CONH-bpy, 5-CONH-bpy) were prepared. Coordination of Re(I)Cl(CO)(3) fragments to the bpy unit gives the corresponding bimetallic Ru~Re complexes 1-3. Hydrogen
Raphael Horvath et al.
Inorganic chemistry, 52(3), 1304-1317 (2013-01-15)
Transition-metal complexes of the types [Re(CO)(3)Cl(NN)], [Re(CO)(3)py(NN)](+), and [Cu(PPh(3))(2)(NN)](+), where NN = 4,4'-bis(5-phenyl-1,3,4-oxadiazol-2-yl)-2,2'-bipyridine (OX) and 4,4'-bis(N,N-diphenyl-4-[ethen-1-yl]-aniline)-2,2'-bipyridine (DPA), have been synthesized and characterized. Crystal structures for [Re(CO)(3)Cl(DPA)] and [Cu(PPh(3))(2)(OX)]BF(4) are presented. The crystal structure of the rhenium complex shows a trans
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