产品名称
铁, powder, <10 μm, ≥99.9% trace metals basis
方案
≥99.9% trace metals basis
表单
powder
反应适用性
core: iron
reagent type: catalyst
电阻率
9.71 μΩ-cm
粒径
<10 μm
沸点
2750 °C (lit.)
mp
1535 °C (lit.)
密度
7.86 g/mL at 25 °C (lit.)
SMILES字符串
[Fe]
InChI
1S/Fe
InChI key
XEEYBQQBJWHFJM-UHFFFAOYSA-N
应用
Iron powder is commonly used as the catalyst for a wide variety of organic transformations. Applications include:
- Reduction of nitroaromatic compounds to aromatic amines.
- Iron-mediated polymerization of methyl methacrylate (MMA) in the presence of a reversible addition-fragmentation chain transfer (RAFT) agent, 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN).
- Synthesis of pyrrolo[1,2-a]quinoxaline derivatives.
- Conversion of ketoximes to the corresponding ketones by treatment with iron powder.
- Iron-catalyzed cross-coupling reaction of imidazoles with vinyl bromides and vinyl chlorides.
警示用语：
Warning
危险声明
危险分类
Flam. Sol. 2 - Self-heat. 2
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
nwg
闪点(°F)
69.8 °F
闪点(°C)
21 °C
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Iron?Catalyzed Cross?Coupling Reaction of Vinyl Bromides or Chlorides with Imidazoles in the Absence of Ligands and Additives.
Mao J, et al.
Advanced Synthesis & Catalysis, 351(9), 1268-1272 (2009)
Reduction of nitroarenes to aromatic amines with nanosized activated metallic iron powder in water.
Wang L, et al.
Synthesis, 2003(13), 2001-2004 (2003)
One-pot synthesis of pyrrolo [1, 2-a] quinoxaline derivatives via iron-promoted aryl nitro reduction and aerobic oxidation of alcohols.
Pereira M D F and Thiery V
Organic Letters, 14(18), 4754-4757 (2012)
Krafft, M. E.; Holton, R. A
The Journal of Organic Chemistry, 49, 3669-3669 (1984)
Krafft, M. E.; Holton, R. A.
Journal of the American Chemical Society, 106, 7619-7619 (1984)
商品
An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.
Higher transition metal silicides are ideal for anisotropic thermoelectric conversion due to their Seebeck coefficient anisotropy and mechanical properties.
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