蒸汽压
0.4 mmHg ( 20 °C)
质量水平
方案
99%
表单
liquid
折射率
n20/D 1.489 (lit.)
沸点
79-81 °C/15 mmHg (lit.)
mp
14-15 °C (lit.)
密度
0.951 g/mL at 25 °C (lit.)
SMILES字符串
N[C@@H]1CCCC[C@H]1N
InChI
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m1/s1
InChI key
SSJXIUAHEKJCMH-PHDIDXHHSA-N
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一般描述
(±)-反式-1,2-二氨基环己烷被广泛用作配位化学和有机催化中的配体。它也充当不对称催化中的非手性配体。（±）-反式-1,2-二氨基环己烷可与脂肪族二醛缩合形成[3+3]或[2+2]大环化产物。
应用
（±）-反式-1,2-二氨基环己烷可用于合成大环[3+3]六席夫碱。它也可用于多齿配体、手性助剂 和手性固定相的合成。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
156.2 °F - closed cup
闪点(°C)
69 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Chirality, 4, 447-447 (1992)
trans-1, 2-Diaminocyclohexane derivatives as chiral reagents, scaffolds, and ligands for catalysis: applications in asymmetric synthesis and molecular recognition
YL Bennani, et al.
Chemical Reviews, 97, 3161-3196 null
Tetrahedron, 49, 4419-4419 (1993)
Enantiopure Monoprotected cis-1, 2-Diaminocyclohexane: One-Step Preparation and Application in Asymmetric Organocatalysis
A Berkessel, et al
ChemCatChem, 2, 1215-1218 (2010)
Marcin Kwit et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(31), 8688-8695 (2007-07-31)
Aliphatic dialdehydes of rigid structures having a cyclohexane, a bicyclo[2.2.2]octane or a [7]triangulane skeleton, have been condensed with enantiomerically pure trans-1,2-diaminocyclohexane to give [3+3] or [2+2] macrocyclization products. Unlike acyclic aliphatic imines, these macrocyclic oligoimines show enhanced stabilities and their
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