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270865

邻苯二硫醇

Name: 邻苯二硫醇
Brand: ALDRICH

96%

别名:

1,2-苯二硫醇

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关于此项目

线性分子式:

C₆H₄(SH)₂

化学文摘社编号:

17534-15-5

分子量:

142.24

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24856407

EC Number:

241-530-4

Beilstein/REAXYS Number:

636154

MDL number:

MFCD00004835

Assay:

96%

Form:

liquid

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属性

Quality Level

200

assay

96%

form

liquid

bp

119-120 °C/17 mmHg (lit.)

mp

22-24 °C (lit.)

solubility

water: slightly soluble

density

1.236 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

Sc1ccccc1S

InChI

1S/C6H6S2/c7-5-3-1-2-4-6(5)8/h1-4,7-8H

InChI key

JRNVQLOKVMWBFR-UHFFFAOYSA-N

说明

General description

已通过紫外-可见光、共振拉曼（rR）和红外（IR）光谱研究了以1,2-苯二硫醇为配体的过渡金属配合物。

Application

1,2-苯二硫醇被用于制备新型席夫碱，该产物是合成新型铜(II)和锌(II)络合物系列所必需的。

pictograms

GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H300 + H310 + H330,H315,H318,H361,H410

pcodes

P202 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

219.2 °F - closed cup

flash_point_c

104 °C - closed cup

ppe

Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lee M, et al.

Royal Society of Chemistry Advances, 5, 86402-86406 (2015)

Vibrational markers for the open-shell character of transition metal bis-dithiolenes: an infrared, resonance raman, and quantum chemical study.

Taras Petrenko et al.

Journal of the American Chemical Society, 128(13), 4422-4436 (2006-03-30)

Transition metal complexes involving the benzene-1,2-dithiol (L(2-)) and Sellmann's 3,5-di-tert-butylbenzene-1,2-dithiol(L(Bu 2-)) ligands have been studied by UV-vis, infrared (IR), and resonance Raman (rR) spectroscopies. Raman spectra were obtained in resonance with the intervalence charge transfer (IVCT) bands in the near-infrared

In vivo and in vitro evaluation of highly specific thiolate carrier group copper(II) and zinc(II) complexes on Ehrlich ascites carcinoma tumor model.

N Raman et al.

European journal of medicinal chemistry, 45(11), 5438-5451 (2010-09-25)

A new series of copper(II) and zinc(II) complexes have been designed and synthesized using a new type of Schiff bases derived from the reaction of 3-(3-phenyl-allylidene)-pentane-2,4-dione with para substituted aniline and benzene-1,2-dithiol. Their structures have been established by analytical and

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全球贸易项目编号

货号	GTIN
270865-500MG	04061837254642