270865
邻苯二硫醇
别名:
1,2-苯二硫醇
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关于此项目
线性分子式:
C6H4(SH)2
化学文摘社编号:
分子量:
142.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-530-4
Beilstein/REAXYS Number:
636154
MDL number:
Form:
liquid
InChI key
JRNVQLOKVMWBFR-UHFFFAOYSA-N
InChI
1S/C6H6S2/c7-5-3-1-2-4-6(5)8/h1-4,7-8H
SMILES string
Sc1ccccc1S
Quality Level
form
liquid
bp
119-120 °C/17 mmHg (lit.)
mp
22-24 °C (lit.)
solubility
water: slightly soluble
density
1.236 g/mL at 25 °C (lit.)
storage temp.
2-8°C
General description
已通过紫外-可见光、共振拉曼（rR）和红外（IR）光谱研究了以1,2-苯二硫醇为配体的过渡金属配合物。
Application
1,2-苯二硫醇被用于制备新型席夫碱，该产物是合成新型铜(II)和锌(II)络合物系列所必需的。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
219.2 °F - closed cup
flash_point_c
104 °C - closed cup
ppe
Eyeshields, Gloves
Lee M, et al.
Royal Society of Chemistry Advances, 5, 86402-86406 (2015)
Taras Petrenko et al.
Journal of the American Chemical Society, 128(13), 4422-4436 (2006-03-30)
Transition metal complexes involving the benzene-1,2-dithiol (L(2-)) and Sellmann's 3,5-di-tert-butylbenzene-1,2-dithiol(L(Bu 2-)) ligands have been studied by UV-vis, infrared (IR), and resonance Raman (rR) spectroscopies. Raman spectra were obtained in resonance with the intervalence charge transfer (IVCT) bands in the near-infrared
N Raman et al.
European journal of medicinal chemistry, 45(11), 5438-5451 (2010-09-25)
A new series of copper(II) and zinc(II) complexes have been designed and synthesized using a new type of Schiff bases derived from the reaction of 3-(3-phenyl-allylidene)-pentane-2,4-dione with para substituted aniline and benzene-1,2-dithiol. Their structures have been established by analytical and
A dinuclear, triple-stranded helicate with a diamide-bridged catechol/benzenedithiol ligand.
F Ekkehardt Hahn et al.
Angewandte Chemie (International ed. in English), 43(36), 4807-4810 (2004-08-19)
Masuma Zawari et al.
Antioxidants (Basel, Switzerland), 8(9) (2019-09-05)
Broccoli sprout powder is a rich source of glucosinolates, which are hydrolysed to isothiocyanates in the presence of the enzyme myrosinase. We showed that in vitro incubation of broccoli sprout powder extract with isolated lymphocytes resulted in the upregulation of
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