270865
邻苯二硫醇
96%
别名:
1,2-苯二硫醇
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关于此项目
线性分子式:
C6H4(SH)2
化学文摘社编号:
分子量:
142.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
241-530-4
Beilstein/REAXYS Number:
636154
MDL number:
产品名称
邻苯二硫醇, 96%
form
liquid
InChI key
JRNVQLOKVMWBFR-UHFFFAOYSA-N
InChI
1S/C6H6S2/c7-5-3-1-2-4-6(5)8/h1-4,7-8H
SMILES string
Sc1ccccc1S
assay
96%
96%
bp
119-120 °C/17 mmHg (lit.)
mp
22-24 °C (lit.)
solubility
water: slightly soluble
density
1.236 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
1,2-苯二硫醇被用于制备新型席夫碱，该产物是合成新型铜(II)和锌(II)络合物系列所必需的。
General description
已通过紫外-可见光、共振拉曼（rR）和红外（IR）光谱研究了以1,2-苯二硫醇为配体的过渡金属配合物。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
219.2 °F - closed cup
flash_point_c
104 °C - closed cup
ppe
Eyeshields, Gloves
N Raman et al.
European journal of medicinal chemistry, 45(11), 5438-5451 (2010-09-25)
A new series of copper(II) and zinc(II) complexes have been designed and synthesized using a new type of Schiff bases derived from the reaction of 3-(3-phenyl-allylidene)-pentane-2,4-dione with para substituted aniline and benzene-1,2-dithiol. Their structures have been established by analytical and
Taras Petrenko et al.
Journal of the American Chemical Society, 128(13), 4422-4436 (2006-03-30)
Transition metal complexes involving the benzene-1,2-dithiol (L(2-)) and Sellmann's 3,5-di-tert-butylbenzene-1,2-dithiol(L(Bu 2-)) ligands have been studied by UV-vis, infrared (IR), and resonance Raman (rR) spectroscopies. Raman spectra were obtained in resonance with the intervalence charge transfer (IVCT) bands in the near-infrared
Lee M, et al.
Royal Society of Chemistry Advances, 5, 86402-86406 (2015)
Luisa Ugolini et al.
Journal of the science of food and agriculture, 99(9), 4235-4241 (2019-02-26)
The antimicrobial activity of allyl-isothiocyanate (AITC) on plant pathogens is well known and has already been demonstrated in the strawberry with respect to Botritis cinerea fungal infection using postharvest biofumigation. In the present study, vapours of 0.08 mg L-1 of Brassica meal-derived
Koji Baba et al.
Inorganic chemistry, 47(7), 2837-2848 (2008-03-12)
Mononuclear Zn, Cd, and Hg 1,2-benzenedithiolates with intramolecular NH...S hydrogen bonds, [M(II){1,2-S2-3,6-(RCONH)2C6H2}2](2-) (R = CH 3, t-Bu; M = Zn, Cd, Hg), were synthesized and characterized by X-ray analysis and spectral measurements. The presence of intramolecular NH...S hydrogen bonds was
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