270954
三(2,2,2-三氟乙烷基)亚磷酸盐
99%
别名:
三（2,2,2-三氟乙氧基）磷化氢
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
(CF3CH2O)3P
化学文摘社编号:
分子量:
328.07
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1714041
Assay:
99%
Form:
liquid
产品名称
三(2,2,2-三氟乙烷基)亚磷酸盐, 99%
InChI
1S/C6H6F9O3P/c7-4(8,9)1-16-19(17-2-5(10,11)12)18-3-6(13,14)15/h1-3H2
SMILES string
FC(F)(F)COP(OCC(F)(F)F)OCC(F)(F)F
InChI key
CBIQXUBDNNXYJM-UHFFFAOYSA-N
assay
99%
form
liquid
refractive index
n20/D 1.324 (lit.)
bp
130-131 °C/743 mmHg (lit.)
density
1.487 g/mL at 25 °C (lit.)
functional group
fluoro
Quality Level
正在寻找类似产品? 访问 产品对比指南
Application
三(2,2,2-三氟乙基)亚磷酸酯通过与2-溴-N-甲氧基-N-甲基乙酰胺发生Arbuzov反应，可以合成N-甲氧基-N-甲基双(2,2,2-三氟乙基)膦酰胺。
General description
三（2,2,2-三氟乙烷基）亚磷酸盐是一种有机磷化合物，可用作有机金属化学中的配体以增进金属簇的结合，并可用作一氧化碳的等效替代物。它也可用作电解质添加剂以改善电化学性能，并可用作锂离子电池中不可燃电解质的共溶剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Samuel Fortin et al.
The Journal of organic chemistry, 67(15), 5437-5439 (2002-07-20)
The N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide was easily obtained via the Arbuzov reaction with use of commercially available tris(2,2,2-trifluoroethyl)phosphite, 2-bromo-N-methoxy-N-methylacetamide, and KF/alumina. The reaction of bis(2,2,2-trifluoroethyl)phosphonate with several aldehydes demonstrates the versatility of the method, which gives Z-unsaturated amides in good yields.
Jiulin Wang et al.
Angewandte Chemie (International ed. in English), 53(38), 10099-10104 (2014-07-26)
Of the various beyond-lithium-ion batteries, lithium-sulfur (Li-S) batteries were recently reported as possibly being the closest to market. However, its theoretically high energy density makes it potentially hazardous under conditions of abuse. Therefore, addressing the safety issues of Li-S cells
Krzysztof Matyjaszewski et al.
Molecules (Basel, Switzerland), 26(2) (2021-01-14)
N-alkyl phosphoranimines were synthesized via the Staudinger reaction of four different alkyl azides with tris(2,2,2-trifluoroethyl) phosphite. N-adamantyl, N-benzyl, N-t-butyl, and N-trityl phosphoranimines were thoroughly characterized and evaluated as chain-capping compounds in the anionic polymerization of P-tris(2,2,2-trifluoroethoxy)-N-trimethylsilyl phosphoranimine monomer. All four
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持